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Ackermann, L. : 2022 Science of Synthesis, 2021/5: Electrochemistry in Organic Synthesis DOI: 10.1055/sos-SD-236-00258
Electrochemistry in Organic Synthesis

13 Electrochemistry in Laboratory Flow Systems

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Herausgeber: Ackermann, L. 

Autoren: Brown, R. C. D. ; Enders, P.; Fang, P.; Folgueiras-Amador, A. A. ; Francke, R. ; Galczynski, J.; Gosmini, C. ; Hodgson, J. W.; Hou, Z.-W.; Huang, H.; Huang, Z.; Inagi, S. ; Kuciński, K. ; Kuriyama, M. ; Lam, K. ; Lambert, T. H.; Leech, M. C. ; Lennox, A. J. J. ; Lin, Z.; Little, R. D.; Massignan, L.; Mei, T.-S.; Meyer, T. H.; Moeller, K. D. ; Onomura, O. ; Prudlik, A.; Ruan, Z. ; Scheremetjew, A. ; Schiltz, P.; Selt, M.; Villani, E. ; Waldvogel, S. R. ; Wang, Z.-H.; Wu, T.; Xing, Y.-K.; Xu, H.-C. ; Yamamoto, K. 

Titel: Electrochemistry in Organic Synthesis

Print ISBN: 9783132442122; Online ISBN: 9783132442146; Buch-DOI: 10.1055/b000000126

1st edition © 2022. Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart

Fachgebiete: Organische Chemie;Chemische Reaktionen, Katalyse;Organometallchemie;Chemische Labormethoden, Stöchiometrie

Science of Synthesis Reference Libraries



Übergeordnete Publikation

Titel: Science of Synthesis

DOI: 10.1055/b-00000101

Reihenherausgeber: Fürstner, A. (Editor-in-Chief); Carreira, E. M.; Faul, M.; Kobayashi, S.; Koch, G.; Molander, G. A.; Nevado, C.; Trost, B. M.; You, S.-L.

Typ: Mehrbändiges Werk

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Abstract

Organic electrosynthesis in flow reactors is an area of increasing interest, with efficient mass transport and high electrode area to reactor volume present in many flow electrolysis cell designs facilitating higher rates of production with high selectivity. The controlled reaction environment available in flow cells also offers opportunities to develop new electrochemical processes. In this chapter, various types of electrochemical flow cells are reviewed in the context of laboratory synthesis, paying particular attention to how the different reactor environments impact upon the electrochemical processes, and the factors responsible for good cell performance. Coverage includes well-established plane-parallel-plate designs, reactors with small interelectrode gaps, extended-channel electrolysis cells, and highly sophisticated designs with rapidly rotating electrodes to enhance mass transport. In each case, illustrative electrosyntheses are presented.

Schlüsselwörter

organic electrochemistry - electrosynthesis - flow chemistry - mass transport - electrochemical cells - reactor design - anodic oxidation - cathodic reduction
 
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