DOI: 10.1055/b-00000121

Synthetic Methods of Organometallic and Inorganic Chemistry (Herrmann/Brauer)

DOI: 10.1055/b-003-108609 Online ISBN 9783131939210
Herrmann, Wolfgang A.: 2000

Transition Metals Part 3

Print ISBN 9783131151414 · Online ISBN 9783131842619
Volume: 9
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Buch

Herausgeber: Herrmann, Wolfgang A.

Titel: Transition Metals Part 3

Print ISBN: 9783131151414; Online ISBN: 9783131842619; Buch-DOI: 10.1055/b-003-108609

2000 © 2000 Georg Thieme Verlag KG
Georg Thieme Verlag, Stuttgart

Fachgebiete: Organometallchemie;Anorganische Chemie

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Übergeordnete Publikation

Titel: Synthetic Methods of Organometallic and Inorganic Chemistry (Herrmann/Brauer)

Online ISBN: 9783131939210; DOI: 10.1055/b-00000121

Typ: Mehrbändiges Werk

Einführung
Chapter 1 Alkenyl, Allyl, and Dienyl Complexes of Main Group Elements and Transition Metals
1.1 Introduction
1.2 1-Alkenyl Compounds
1.3 Allyl Compounds
1.4 Dienyl Compounds
1.5 Polyenyl Metal Complexes
Chapter 2 π-Complexes with Heterocyclic Ligands
2.1 Introduction
2.2 Pentamethylpyrrole Complexes
2.3 (η5-Pyrrolyl)tricarbonylmanganese (Azacymantrene)
2.4 (η5-Cyclopentadienyl)(η5-1H-pyrrol-1-y1)iron (Azaferrocene)
2.5 2,5-Di-tert.-butyl-l-azacyclopentadienylmetal Complexes
2.6 η5-Phospholy1 Complexes of Early Transition Metals
2.7 4,5-Diphenyl-1,3-Diphospholide Anion and (η5-4,5-Dipheny1-1,3-diphospholy1)(η5-cyclopentadienyl)iron
2.8 2,2',5,5'-Tetrakis(trimethylsilyl)-3,3',4,4'-tetramethyl-1,1'-distibaferrocene
2.9 Bis(1-tert.-butyl-2-methyl-1H-1,2-azaborolyl)iron and (1-tert.-Buty1-2-methy1-1H-1,2-azaborolyl)(dicarbonyl)cobalt
Chapter 3 Complexes of N-Heterocyclic Carbenes
3.1 Introduction
3.2 High-Yielding Synthesis of Functionalized N-Heterocyclic Carbenes in Liquid Ammonia
3.3 Synthesis of NHC Complexes by a Metalla-Ugi Reaction
3.4 Nickel(II) Complexes
3.5 Nickel(0) Complexes
3.6 Palladium(II) Complexes
3.7 Immobilization of Pd(II)-NHC Complexes
3.8 Palladium(0) Complexes
3.9 Iridium(III) Complexes
3.10 Ruthenium(II) Complexes
Chapter 4 Oxo- and Alkoxy-Complexes
4.1 Alkyltrioxometal Compounds
4.2 Oxohalides of Molybdenum and Tungsten
4.3 Trichlorooxotungsten Compounds with Pyridyl Alcoholate Ligands
4.4 Dioxomolybdenum and -tungsten Compounds with Pyridyl Alcoholate Ligands
4.5 Other Complexes with Pyridyl Alcoholate Ligands
4.6 Solvent Adducts of (Dibromo)dioxomolybdenum(VI)
4.7 Lewis Base Adducts of Dihalodioxomolybdenum(VI)
4.8 Trigonal Bipyramidal Lewis Base Adducts of Methyltrioxorhenium(VII)
Chapter 5 Highly Reduced Tantalum Carbonyls Derived from the Hexacarbonyltantalum Anion
5.1 Hexacarbonyltantalates(1–)
5.2 Pentacarbonyltantalates(3–)
5.3 Pentacarbonylhydridotantalates(2–)
5.4 (Ammine)(pentacarbonyl)tantalates(1–)
5.5 (tert.-Butyl Isocyanide)(pentacarbonyl)tantalates(1–)
5.6 (Cyano)(pentacarbonyl)tantalates(2–)
Chapter 6 Water-Soluble Metal Complexes of Sulfonated Triphenylphosphane (TPPTS)
6.1 Introduction
6.2 General Remarks
6.3 Gel Permeation Chromatography
6.4 Sulfonated Phosphanes
6.5 TPPTS-Metal Complexes
Chapter 7 Miscellaneous Complexes
7.1 (Pentamethylcyclopentadienyl)(phosphane)ruthenium Complexes
7.2 Allyl and Phosphane Complexes of Palladium
7.3 A Selection of Important Alkylidene-Metal Complexes
7.4 Bisimino Systems (Brookhart/Gibson Systems)
Anhang
Anhang