Abstract
A personalized account is presented that reveals the real stories
behind the development of copper hydride chemistry at UCSB over
the past decade: names, events, and the thinking behind the discoveries.
Both achirally ligated and nonracemically complexed copper hydride
reagents are discussed within the context of the field as a whole.
1 Introduction
2 Early Ligand Effects
3 The BIPHEP Story
4 Enter JOSIPHOS
5 Copper Hydride + SEGPHOS: Another Great Match
6 Copper Hydride Contained... in a Bottle
7 (BDP)CuH: A ‘Hot’ Achiral Source of Copper
Hydride
8 New Areas for Copper Hydride Chemistry
8.1 Reductive Aldol Reactions
8.2 Copper Hydride Chemistry in Water
9 Summary and Outlook
Key words
ligands - asymmetric catalysis - copper hydride - hydrosilylations - asymmetric catalysis
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