Synthesis 2012; 44(22): 3465-3476
DOI: 10.1055/s-0032-1316785
paper
© Georg Thieme Verlag Stuttgart · New York

Benzothiadiazoloperylenes and Benzoxadiazoloperylenes: Amorphous Functional Materials

Heinz Langhals*
Department of Chemistry, Ludwig-Maximilians-Universität München, Butenandtstr. 5-13, Haus F, 81377 München, Germany   Fax: +49(89)218077640   Email: [email protected]   Fax: +49(89)218077680   Email: [email protected]
,
Paul Knochel
Department of Chemistry, Ludwig-Maximilians-Universität München, Butenandtstr. 5-13, Haus F, 81377 München, Germany   Fax: +49(89)218077640   Email: [email protected]   Fax: +49(89)218077680   Email: [email protected]
,
Andreas Walter
Department of Chemistry, Ludwig-Maximilians-Universität München, Butenandtstr. 5-13, Haus F, 81377 München, Germany   Fax: +49(89)218077640   Email: [email protected]   Fax: +49(89)218077680   Email: [email protected]
,
Silvia Zimdars
Department of Chemistry, Ludwig-Maximilians-Universität München, Butenandtstr. 5-13, Haus F, 81377 München, Germany   Fax: +49(89)218077640   Email: [email protected]   Fax: +49(89)218077680   Email: [email protected]
› Author Affiliations
Further Information

Publication History

Received: 23 August 2012

Accepted after revision: 27 August 2012

Publication Date:
31 October 2012 (online)


Abstract

2,1,3-Benzothiadiazole or 2,1,3-benzoxadiazole were magnesiated (TMP2Mg·2LiCl) and efficiently attached to perylene and benzoperylene building blocks providing amorphous light-­absorbing materials where FRET energy transfer proceeds between the 2,1,3-benzothiadiazole or 2,1,3-benzoxadiazole and the perylene units. Some of these new materials were obtained as amorphous solids of interest for material science.

 
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