Benzothiadiazoloperylenes and Benzoxadiazoloperylenes: Amorphous Functional Materials

Heinz Langhals; Paul Knochel; Andreas Walter; Silvia Zimdars

doi:10.1055/s-0032-1316785

Synthesis, Inhaltsverzeichnis

Synthesis 2012; 44(22): 3465-3476
DOI: 10.1055/s-0032-1316785

paper

Benzothiadiazoloperylenes and Benzoxadiazoloperylenes: Amorphous Functional Materials

Heinz Langhals*

Department of Chemistry, Ludwig-Maximilians-Universität München, Butenandtstr. 5-13, Haus F, 81377 München, Germany Fax: +49(89)218077640 eMail: Langhals@lrz.uni-muenchen.de Fax: +49(89)218077680 eMail: Paul.Knochel@cup.uni-muenchen.de

,

Paul Knochel

Department of Chemistry, Ludwig-Maximilians-Universität München, Butenandtstr. 5-13, Haus F, 81377 München, Germany Fax: +49(89)218077640 eMail: Langhals@lrz.uni-muenchen.de Fax: +49(89)218077680 eMail: Paul.Knochel@cup.uni-muenchen.de

,

Andreas Walter

Department of Chemistry, Ludwig-Maximilians-Universität München, Butenandtstr. 5-13, Haus F, 81377 München, Germany Fax: +49(89)218077640 eMail: Langhals@lrz.uni-muenchen.de Fax: +49(89)218077680 eMail: Paul.Knochel@cup.uni-muenchen.de

,

Silvia Zimdars

Department of Chemistry, Ludwig-Maximilians-Universität München, Butenandtstr. 5-13, Haus F, 81377 München, Germany Fax: +49(89)218077640 eMail: Langhals@lrz.uni-muenchen.de Fax: +49(89)218077680 eMail: Paul.Knochel@cup.uni-muenchen.de

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Abstract

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Abstract

2,1,3-Benzothiadiazole or 2,1,3-benzoxadiazole were magnesiated (TMP₂Mg·2LiCl) and efficiently attached to perylene and benzoperylene building blocks providing amorphous light-absorbing materials where FRET energy transfer proceeds between the 2,1,3-benzothiadiazole or 2,1,3-benzoxadiazole and the perylene units. Some of these new materials were obtained as amorphous solids of interest for material science.

Key words

arenes - heterocycles - imides - cross-coupling fused-ring systems - zinc

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Referenzen

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