Three-Component Carboboration of Alkenes under Copper Catalysis

Ikuo Kageyuki; Hiroto Yoshida; Ken Takaki

doi:10.1055/s-0033-1341267

Synthesis, Table of Contents

Synthesis 2014; 46(14): 1924-1932
DOI: 10.1055/s-0033-1341267

special topic

Three-Component Carboboration of Alkenes under Copper Catalysis

Authors

Ikuo Kageyuki

Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, Higashi-Hiroshima 739-8527, Japan Fax: +81(82)4245494 Email: yhiroto@hiroshima-u.ac.jp
Hiroto Yoshida*

Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, Higashi-Hiroshima 739-8527, Japan Fax: +81(82)4245494 Email: yhiroto@hiroshima-u.ac.jp
Ken Takaki

Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, Higashi-Hiroshima 739-8527, Japan Fax: +81(82)4245494 Email: yhiroto@hiroshima-u.ac.jp

Abstract

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Abstract

Three-component carboboration of alkenes takes place efficiently by the reaction with a diboron compound and carbon electrophiles with the aid of a copper–NHC catalyst. The carboboration afforded diverse multisubstituted borylalkanes via the regioselective formation of carbon–boron and carbon–carbon bonds.

Key words

alkenes - carboboration - copper - equol - multicomponent reaction

Full Text

References

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