Microwave-Assisted Oxidation of Alcohols Using Zinc Polyoxometalate

Wiktor Kasprzyk; Mateusz Galica; Szczepan Bednarz; Dariusz Bogdał

doi:10.1055/s-0034-1379211

Synlett, Table of Contents

Synlett 2014; 25(19): 2757-2760
DOI: 10.1055/s-0034-1379211

letter

Microwave-Assisted Oxidation of Alcohols Using Zinc Polyoxometalate

Authors

Wiktor Kasprzyk*

Department of Biotechnology and Physical Chemistry, Faculty of Chemical Engineering and Technology, Cracow University of Technology, Warszawska 24 St., 31-155 Krakow, Poland Fax: +48(12)6342425 Email: jumper.wk@gmail.com
Mateusz Galica

Department of Biotechnology and Physical Chemistry, Faculty of Chemical Engineering and Technology, Cracow University of Technology, Warszawska 24 St., 31-155 Krakow, Poland Fax: +48(12)6342425 Email: jumper.wk@gmail.com
Szczepan Bednarz

Department of Biotechnology and Physical Chemistry, Faculty of Chemical Engineering and Technology, Cracow University of Technology, Warszawska 24 St., 31-155 Krakow, Poland Fax: +48(12)6342425 Email: jumper.wk@gmail.com
Dariusz Bogdał

Department of Biotechnology and Physical Chemistry, Faculty of Chemical Engineering and Technology, Cracow University of Technology, Warszawska 24 St., 31-155 Krakow, Poland Fax: +48(12)6342425 Email: jumper.wk@gmail.com

Abstract

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Abstract

In the presence of 30% aqueous hydrogen peroxide and [WZn₃(H₂O)₂][ZnW₉O₃₄)₂]^12– polyoxometalate as a catalyst, primary and secondary alcohols were oxidized to carboxylic acids and ketones, respectively, in short reaction times (ca. 15 min) under microwave-pressurized conditions.

Key words

oxidation - hydrogen peroxide - catalysis - alcohols - microwave irradiation

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References

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Supplementary Material

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