Applications of Metal Nanopore Catalysts in Organic Synthesis

Balaram S. Takale; Ming Bao; Yoshinori Yamamoto; Abdulrahman I. Almansour; Natarajan Arumugam; Raju Suresh Kumar

doi:10.1055/s-0034-1380867

Synlett, Table of Contents

Synlett 2015; 26(17): 2355-2380
DOI: 10.1055/s-0034-1380867

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Applications of Metal Nanopore Catalysts in Organic Synthesis

Authors

Balaram S. Takale

^aState Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116023, P. R. of China Email: mingbao@dlut.edu.cn Email: yoshi@dlut.edu.cn
Ming Bao*

^aState Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116023, P. R. of China Email: mingbao@dlut.edu.cn Email: yoshi@dlut.edu.cn
Yoshinori Yamamoto*

^aState Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116023, P. R. of China Email: mingbao@dlut.edu.cn Email: yoshi@dlut.edu.cn

^bWPI Advanced Institute for Materials Research, Tohoku University, Sendai 980-8577, Japan Email: yoshi@m.tohoku.ac.jp
Abdulrahman I. Almansour

^cDepartment of Chemistry, College of Sciences, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi Arabia
Natarajan Arumugam

^cDepartment of Chemistry, College of Sciences, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi Arabia
Raju Suresh Kumar

^cDepartment of Chemistry, College of Sciences, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi Arabia

Abstract

All articles of this category

This account is dedicated to the memory of Professor Manfred Schlosser for his outstanding contributions to organometallic chemistry.

Abstract

Reducing the size of bulk metals to nanometer scale can result in the display of extraordinary physical and chemical properties. Typically, metal nanoparticles (MNPs) are prepared from metal atoms or metal salts and show remarkable catalytic properties. Metal nanopores (MNPores) are prepared through a totally reverse approach (from bulk metal to nanosized metal): alloy M¹M² is fabricated from metal M¹ and metal M², and then dealloying of M² results in a nanoporous framework of metal M¹. This account summarizes MNPore-catalyzed reactions developed in our group, and their comparison with other representative catalytic reactions.

1 Introduction

1.1 Fabrication and Structural Characteristics of Nanoporous Gold

2 Oxidation Reactions

2.1 Oxidation of Alcohols

2.2 Synthesis of Formamides Through Oxidative Coupling of Methanol with Amines

2.3 Oxidation of Silanes

3 Reduction Reactions

3.1 Semihydrogenation of Alkynes

3.2 Reduction of Quinoline

3.3 Reduction of Imines and Reductive Amination of Carbonyls

3.4 Reduction of α,β-Unsaturated Aldehydes

3.5 1,4-Hydrosilylation of Cyclic Enones

4 Formation of C–Si, C–B, and C–C Bonds Using Alkynes

4.1 Hydrosilylation of Alkynes

4.2 Diboration of Alkynes

4.3 Benzannulation Reaction

5 CuNPore-Catalyzed Click Reaction

6 Suzuki, Negishi and Heck Coupling Reactions

7 Concluding Remarks

Key words

metal nanoparticle catalysts - metal nanopore catalysts - nanoparticles - nanopores - heterogeneous - homogeneous - oxidation - reduction

Full Text

References

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