Experimental Electrochemical Potentials of Nickel Complexes

Qiao Lin; Gregory Dawson; Tianning Diao

doi:10.1055/s-0040-1719829

Synlett, Table of Contents

Synlett 2021; 32(16): 1606-1620
DOI: 10.1055/s-0040-1719829

new tools

Modern Nickel-Catalyzed Reactions

Experimental Electrochemical Potentials of Nickel Complexes

Authors

Qiao Lin
Gregory Dawson
Tianning Diao ∗

Abstract

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Abstract

Nickel-catalyzed cross-coupling and photoredox catalytic reactions has found widespread utilities in organic synthesis. Redox processes are key intermediate steps in many catalytic cycles. As a result, it is pertinent to measure and document the redox potentials of various nickel species as precatalysts, catalysts, and intermediates. The redox potentials of a transition-metal complex are governed by its oxidation state, ligand, and the solvent environment. This article tabulates experimentally measured redox potentials of nickel complexes supported on common ligands under various conditions. This review article serves as a versatile tool to help synthetic organic and organometallic chemists evaluate the feasibility and kinetics of redox events occurring at the nickel center, when designing catalytic reactions and preparing nickel complexes.

1 Introduction

1.1 Scope

1.2 Measurement of Formal Redox Potentials

1.3 Redox Potentials in Nonaqueous Solution

2 Redox Potentials of Nickel Complexes

2.1 Redox Potentials of (Phosphine)Ni Complexes

2.2 Redox Potentials of (Nitrogen)Ni Complexes

2.3 Redox Potentials of (NHC)Ni Complexes

Key words

redox potentials - nickel - cyclic voltammetry - reduction - oxidation

Full Text

References

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