CC BY 4.0 · Eur J Dent 2024; 18(01): 104-108
DOI: 10.1055/s-0040-1721315
Original Article

Flexural Strength of an Indirect Composite Modified with Single-Wall Carbon Nanotubes

Pedro Rogério Camargos Pennisi
1   School of Dentistry, Federal University of Uberlândia, Uberlândia/MG, Brazil
,
Pedro Urquiza Jayme Silva
1   School of Dentistry, Federal University of Uberlândia, Uberlândia/MG, Brazil
,
Fábio Scorsolini Valverde
2   School of Dentistry, University Center - UNIFAE, São João da Boa Vista/Sao Paolo, Brazil
,
Ticiane Campos Clemente
2   School of Dentistry, University Center - UNIFAE, São João da Boa Vista/Sao Paolo, Brazil
,
Vitória Cerri
2   School of Dentistry, University Center - UNIFAE, São João da Boa Vista/Sao Paolo, Brazil
,
Maria Eduarda Biaco
2   School of Dentistry, University Center - UNIFAE, São João da Boa Vista/Sao Paolo, Brazil
,
Rebeca Garcia Rosa Ferreira
3   School of Physiotherapy, University Center - UNIFAE, São João da Boa Vista, Brazil
,
Luiz Renato Paranhos
1   School of Dentistry, Federal University of Uberlândia, Uberlândia/MG, Brazil
,
Eduardo Buozi Moffa
4   College of Dentistry, University of Saskatchewan, Saskatoon, SK, Canada
› Author Affiliations
Funding This study received its funding from the Coordination of Superior Level Staff Improvement, (finance code 001) and the National Council for Scientific and Technological Development.

Abstract

Objectives The low resistance to fracture has limited the use of indirect composite resins for dental restorations, particularly in regions that are exposed to strong occlusal forces. To overcome this issue, different types of reinforcement for composites have been proposed, one of which is carbon nanotubes (CNTs). The aim of this study was to evaluate the flexural resistance of one commercial indirect composite resin (Sinfony, 3M/ESPE) after incorporation of single-wall carbon nanotubes (SWCNTs; Sigma–Aldrich, Inc., St. Louis, Missouri, United States) with or without the silanization form.

Materials and Methods Specimens of composite resin were fabricated in a Teflon mold. The composite resin was prepared according to the manufacturer’s instructions (n = 10 for each group), with SWCNTs in three concentrations.

Statistical Analysis The SWCNTs and SWCNT/SiO2-ATES specimens were evaluated by transmission electron microscopy, and a flexural test was conducted according to the ISO 4049/2009. Flexural strength data in MPa were submitted to one-way ANOVA following Tukey (p < 0.05).

Results The SWCNTs did not improve the flexural strength of indirect composite resin when compared with the control, independent of the concentration added (p > 0.05). However, when SWCNTs and SWCNTs/SiO2-ATES were compared, the SWCNTs/SiO2-ATES showed higher values than the three concentrations of SWCNTs (p < 0.05).

Conclusion The silanization process improves the SWCNTs strength proprieties, but the modification of chemical bonding between SWCNT and SWCNT/SiO2-ATES modified resins, in different concentrations, did not improve the composite resin flexural strength.



Publication History

Article published online:
31 May 2021

© 2021. The Author(s). This is an open access article published by Thieme under the terms of the Creative Commons Attribution License, permitting unrestricted use, distribution, and reproduction so long as the original work is properly cited. (https://creativecommons.org/licenses/by/4.0/)

Thieme Medical and Scientific Publishers Pvt. Ltd.
A-12, 2nd Floor, Sector 2, Noida-201301 UP, India

 
  • References

  • 1 Suzuki S, Nagai E, Taira Y, Minesaki Y. In vitro wear of indirect composite restoratives. J Prosthet Dent 2002; 88 (04) 431-436
  • 2 Jordan RE, Suzuki M. Posterior composite restorations. Where and how they work best. J Am Dent Assoc 1991; 122 (11) 30-37
  • 3 Lacy AM. A critical look at posterior composite restorations. J Am Dent Assoc 1987; 114 (03) 357-362
  • 4 Manhart J, Chen H, Hamm G, Hickel R. Buonocore Memorial Lecture. Review of the clinical survival of direct and indirect restorations in posterior teeth of the permanent dentition. Oper Dent 2004; 29 (05) 481-508
  • 5 Wilder Jr. AD, Bayne SC, Heymann HO. Long-term clinical performance of direct posterior composites. Trans Acad Dent Mater 1996; 9 (33) 151-169
  • 6 Kim KH, Ong JL, Okuno O. The effect of filler loading and morphology on the mechanical properties of contemporary composites. J Prosthet Dent 2002; 87 (06) 642-649
  • 7 Ellakwa AE, Shortall AC, Marquis PM. Influence of fiber type and wetting agent on the flexural properties of an indirect fiber reinforced composite. J Prosthet Dent 2002; 88 (05) 485-490
  • 8 Freilich MA, Duncan JP, Meiers JC, Goldberg AJ. Preimpregnated, fiber-reinforced prostheses. Part I. Basic rationale and complete-coverage and intracoronal fixed partial denture designs. Quintessence Int 1998; 29 (11, Suppl 11/01): 689-696
  • 9 Ausman KD, Piner R, Lourie O, Ruoff RS, Korobov M. Organic solvent dispersions of single-walled carbon nanotubes: toward solutions of pristine Nanotubes. J Phys Chem B 2000; 104 (38) 8911-8915
  • 10 Lourie O, Wagner HD. Transmission electron microscopy observations of fracture of single-wall carbon nanotubes under axial tension. Appl Phys Lett 1998; 73 (24) 3527-3529
  • 11 Schadler LS, Giannaris SC, Ajayan PM. Load transfer in carbon nanotube epoxy composites. Appl Phys Lett 1998; 73 (26) 3842-3844
  • 12 Behr M, Rosentritt M, Latzel D, Kreisler T. Comparison of three types of fiber-reinforced composite molar crowns on their fracture resistance and marginal adaptation. J Dent 2001; 29 (03) 187-196
  • 13 Lehmann F, Eickemeyer G, Rammelsberg P. Fracture resistance of metal-free composite crowns-effects of fiber reinforcement, thermal cycling, and cementation technique. J Prosthet Dent 2004; 92 (03) 258-264
  • 14 Brunton PA, Cattell P, Burke FJ, Wilson NH. Fracture resistance of teeth restored with onlays of three contemporary tooth-colored resin-bonded restorative materials. J Prosthet Dent 1999; 82 (02) 167-171
  • 15 Ellakwa A, Thomas GD, Shortall AC, Marquis PM, Burke FJ. Fracture resistance of fiber-reinforced composite crown restorations. Am J Dent 2003; 16 (06) 375-380
  • 16 Moniruzzaman M, Winey KL. Polymer nanocomposites containing carbon nanotubes. Macromolecules 2006; 39 (16) 5194-5195
  • 17 Dasa A, Stöckelhubera KW, Jurka R. et al. Modified and unmodified multiwalled carbon nanotubes in high performance solution-styrene-butadiene and butadiene rubber blends. Polymer (Guildf) 2008; 49 (24) 5276-5283
  • 18 Gong X, Liu J, Baskaran S, Voise RD, Young JS. Surfactant-assisted processing of carbon nanotube/polymer composites. Chem Mater 2000; 12 (04) 1049-1052
  • 19 Xie XL, Maia YW, Zhou XP. Dispersion and alignment of carbon nanotubes in polymer matrix: A review. Mater Sci Eng 2005; 49 (04) 89-112
  • 20 Wanga YP, Chenga RL, Lianga LL, Wang YM. Study on the preparation and characterization of ultra-high molecular weight polyethylene-carbon nanotubes composite fiber. Compos Sci Technol 2005; 65 (05) 793-797
  • 21 Krithikadatta J, Gopikrishna V, Datta M. CRIS Guidelines (checklist for reporting in-vitro studies): a concept note on the need for standardized guidelines for improving quality and transparency in reporting in-vitro studies in experimental dental research. J Conserv Dent 2014; 17 (04) 301-304
  • 22 Zhang F, Xia Y, Xu L, Gu N. Surface modification and microstructure of single-walled carbon nanotubes for dental resin-based composites. J Biomed Mater Res B Appl Biomater 2008; 86 (01) 90-97
  • 23 Xia Y, Zhang F, Xie H, Gu N. Nanoparticle-reinforced resin-based dental composites. J Dent 2008; 36 (06) 450-455
  • 24 Prolongo SG, Gude MR, Ureña A. Synthesis and characterisation of epoxy resins reinforced with carbon nanotubes and nanofibers. J Nanosci Nanotechnol 2009; 9 (10) 6181-6187
  • 25 Xu HH, Quinn JB, Giuseppetti AA, Eichmiller FC, Parry EE, Schumacher GE. Three-body wear of dental resin composites reinforced with silica-fused whiskers. Dent Mater 2004; 20 (03) 220-227
  • 26 Terry DA. Direct applications of a nanocomposite resin system: Part 1–the evolution of contemporary composite materials. Pract Proced Aesthet Dent 2004; 16 (06) 417-422