Recent Development of Novel Organic Reactions Controlled by Silicon

Jih Ru Hwu; Himatkumar V. Patel

doi:10.1055/s-1995-5153

Synlett 1995; 1995(10): 989-996
DOI: 10.1055/s-1995-5153

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Recent Development of Novel Organic Reactions Controlled by Silicon

Jih Ru Hwu^* , Himatkumar V. Patel

^*Organosilicon and Synthesis Laboratory, Department of Chemistry, National Tsing Hua University, Hsinchu, Taiwan 30043, Republic of China and Institute of Chemistry, Academia Sinica, Nankang, Taipei, Taiwan 11529, Republic of China, Fax 886 35 721594; 886 2 7881337; Bitnet JRHwu@chem.nthu.edu.tw; ChemHwu@chem.as.tw

Abstract

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By virtue of its ability to stabilize neighboring cations and radicals, even when as remote as in the γ-position, silicon can direct, promote, or assist reactions that are, in its absence, difficult or messy or both or even altogether impossible. Presented below is a brief account of part of our recent work on the use of silicon to control organic reactions.

Silicon - directed - promoted - controlled - assisted

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