Synfacts 2005(1): 0163-0163  
DOI: 10.1055/s-2005-872136
Metal-Mediated Synthesis
© Georg Thieme Verlag Stuttgart · New York

BF3-Substituted 1,3-Dienes and Their Diels-Alder/Cross-Coupling Reactions

Contributor(s): Paul Knochel, Andrei Gavryushin
S. De, M. E. Welker*
Wake Forest University, NC, USA
Further Information

Publication History

Publication Date:
21 September 2005 (online)


1,3-Dienyl-2-trifluoroborates, prepared for the first time, are a new class of heterosubstituted dienes, sufficiently stable for storage for a long time. They are reactive in cross-coupling as well as in Diels-Alder reactions.