BF3-Substituted 1,3-Dienes and Their Diels-Alder/Cross-Coupling Reactions

S. De; M. E. Welker

doi:10.1055/s-2005-872136

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Synfacts 2005(1): 0163-0163
DOI: 10.1055/s-2005-872136

Metal-Mediated Synthesis

BF₃-Substituted 1,3-Dienes and Their Diels-Alder/Cross-Coupling Reactions

Contributor(s): Paul Knochel, Andrei Gavryushin
S. De, M. E. Welker*
Wake Forest University, NC, USA

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Publication History

Publication Date:
21 September 2005 (online)

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Significance

1,3-Dienyl-2-trifluoroborates, prepared for the first time, are a new class of heterosubstituted dienes, sufficiently stable for storage for a long time. They are reactive in cross-coupling as well as in Diels-Alder reactions.