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Synfacts 2010(11): 1248-1248
DOI: 10.1055/s-0030-1258738
DOI: 10.1055/s-0030-1258738
Synthesis of Materials and Unnatural Products
© Georg Thieme Verlag
Stuttgart ˙ New YorkMetal-Containing Conducting Polymers
W. Liu, W. Huang, M. Pink, D. Lee*
Indiana University, Bloomington and Carl Zeiss SMT Inc., Peabody, USA
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
21. Oktober 2010 (online)
Significance
A series of metal cage complexes 1, formed by the [2+3]-type cocondensation of a π-extended boronic acid and dioxime is reported. The materials formed following electrochemical polymerization are shown to retain the redox properties of the coordinated metal. Furthermore, consecutive electropolymerization using two different monomers formed bilayer metal containing conducting polymers (MCPs) having different metals in each layer.