Abstract
The synthesis of organic thiosulfates, up to 10 nm in length, which were tailored
for generating artificial monomembranes on gold surfaces by electrochemically initiated
deposition, was accomplished. (E )-3-(4-Hydroxyphenyl)acrylic acid (4-hydroxy cinnamic acid) was employed as aromatic
head group and (C10 H20 -O-)n (n = 1, 3, 5, 7) building blocks were attached. The synthetic procedure comprises
a series of nucleophilic substitutions under carefully defined conditions. Extended
purification is crucial for eliminating non-reacted starting materials.
Key words
self-assembled monolayer (SAM) - organic thiosulfates (Bunte salts) - oligoether -
long-chain surfactants - nucleophilic substitution
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