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Synthesis 2022; 54(06): 1652-1660
DOI: 10.1055/a-1690-4840
DOI: 10.1055/a-1690-4840
paper
Solvent- and Metal-Controlled Regiodivergent Synthesis of Trifluoromethylated Pyrazol-3-yl- and Pyrazol-5-ylphosphonates
A. Yu. Mitrofanov is grateful to the Russian Science Foundation (RSF, grant no. 19-73-00168, development of the synthesis of 1). I. P. Beletskaya thanks the Russian Science Foundation (RSF, grant no. 19-13-00223, synthesis of pyrazoles 3 and 5).
Abstract
Convenient approaches to the selective syntheses of trifluoromethylated pyrazol-3-yl- and pyrazol-5-ylphosphonates have been developed based on solvent- and metal-controlled reaction of diethyl (4,4,4-trifluoro-3-oxobut-1-yn-1-yl)phosphonate and monosubstituted hydrazines.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-1690-4840.
- Supporting Information
Publikationsverlauf
Eingereicht: 15. September 2021
Angenommen nach Revision: 08. November 2021
Accepted Manuscript online:
08. November 2021
Artikel online veröffentlicht:
04. Januar 2022
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