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Paul, Knochel: 50 Years SYNTHESIS – Golden Anniversary Issue

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50 Years SYNTHESIS – Golden Anniversary Issue Part II

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Trost, Barry M.; Schultz, Johnathan E.: Palladium-Catalyzed Asymmetric Allylic Alkylation Strategies for the Synthesis of Acyclic Tetrasubstituted Stereocenters

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Grogg, Marcel; Hilvert, Donald; Beck, Albert K.; Seebach, Dieter: Syntheses of Cyanophycin Segments for Investigations of Cell-Penetration

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Murai, Masahito; Takai, Kazuhiko: Unsymmetrical Difunctionalization of Two Different C–H Bonds in One Pot Under Transition-Metal Catalysis

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Karageorgis, George; Waldmann, Herbert: Guided by Evolution: Biology-Oriented Synthesis of Bioactive Compound Classes

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Barrett, Anthony G. M.; Ma, Tsz-Kan; Mies, Thomas: Recent Developments in Polyene Cyclizations and Their Applications in Natural Product Synthesis

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Zhang, Heng; Lei, Aiwen: Electrochemical/Photochemical Aminations Based on Oxidative Cross-Coupling between C–H and N–H

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Piccardi, Riccardo; Turcaud, Serge; Benedetti, Erica; Micouin, Laurent: Synthesis and Reactivity of Mixed Dimethylalkynylaluminum Reagents

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Kiefer, Alexander; Kazmaier, Uli: Syntheses of Cyclomarins – Interesting Marine Natural Products with Distinct Mode of Action towards Malaria and Tuberculosis

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Wu, Xiang; Gong, Liu-Zhu: Palladium(0)-Catalyzed Difunctionalization of 1,3-Dienes: From Racemic to Enantioselective

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Yoshikai, Naohiko: Recent Advances in Enantioselective C–C Bond Formation via Organocobalt Species

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Erb, William; Mongin, Florence: Twofold Ferrocene C–H Lithiations For One-Step Difunctionalizations

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Lübken, Dennis; Saxarra, Marius; Kalesse, Markus: Tris(acetylacetonato) Iron(III): Recent Developments and Synthetic Applications

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Barde, E.; Guérinot, A.; Cossy, J.: α-Arylation of Amides from α-Halo Amides Using Metal-Catalyzed Cross-Coupling Reactions

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Kumagai, Naoya; Shibasaki, Masakatsu: 7-Azaindoline Auxiliary: A Versatile Attachment Facilitating Enantioselective C–C Bond-Forming Catalysis

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Stopka, Tobias; Adler, Pauline; Hagn, Gerhard; Zhang, Haoqi; Tona, Veronica; Maulide, Nuno: Electrophilic Activation of Amides for the Preparation of Polysubstituted Pyrimidines

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Supporting Information

Bartlett, Samuel L.; Keiter, Kimberly M.; Zavesky, Blane P.; Johnson, Jeffrey S.: Formation of Complex α-Imino Esters via Multihetero-Cope Rearrangement of α-Keto Ester Derived Nitrones

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McCabe, Stephanie R.; Wipf, Peter: Asymmetric Total Synthesis and Biological Evaluation of (+)-Cycloclavine

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Endoma-Arias, Mary Ann A.; Makarova, Mariia; Dela Paz, Helen E.; Hudlicky, Tomas: Chemoenzymatic Total Synthesis of (+)-Oxycodone from Phenethyl Acetate

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Xue, Weichao; Oestreich, Martin: Silicon Grignard Reagents as Nucleophiles in Transition-Metal-Catalyzed Allylic Substitution

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Sato, Io; Yamashita, Yasuhiro; Kobayashi, Shū: Alkylpotassium-Catalyzed Benzylic C–H Alkylation of Alkylarenes with Alkenes

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Nitelet, Antoine; Kairouz, Vanessa; Lebel, Hélène; Charette, André B.; Evano, Gwilherm: Continuous Flow Chlorination of Alkenyl Iodides Promoted by Copper Tubing

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Noguchi, Teppei; Nishii, Yuji; Miura, Masahiro: Rhodium-Catalyzed Cascade Annulative Coupling of 3,5-Diarylisoxazoles with Alkynes

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Wang, Han; Zhang, Duo; Cao, Mengwei; Bolm, Carsten: Electrophilic Sulfoximidations of Thiols by Hypervalent Iodine Reagents

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Gao, Wen-Chao; Xiong, Zi-Yue; Pirhaghani, Shafigh; Wirth, Thomas: Enantioselective Electrochemical Lactonization Using Chiral Iodoarenes as Mediators

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Konstantinova, Olga V.; Koskinen, Ari M.P.: Synthesis of the C1–C12 Fragment of Calyculin C

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Supporting Information

Bartolo, Nicole D.; Hornstein, Alana L.; Zhao, Annie Y.; Woerpel, K. A.: Diastereoselectivities in Reductions of α-Alkoxy Ketones Are Not Always Correlated to Chelation-Induced Rate Acceleration

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Krieck, Sven; Schüler, Philipp; Peschel, Jan M.; Westerhausen, Matthias: Straightforward One-Pot Syntheses of Silylamides of Magnesium and Calcium via an In Situ Grignard Metalation Method

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Stöckl, Yannick; Frey, Wolfgang; Lang, Johannes; Claasen, Birgit; Baro, Angelika; Laschat, Sabine: Asymmetric Organocatalysis Revisited: Taming Hydrindanes with Jørgensen–Hayashi Catalyst

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Supporting Information

Schober, Lukas; Ratnam, Shahilan; Yamashita, Yasunobu; Adebar, Niklas; Pieper, Matthias; Berkessel, Albrecht; Hessel, Volker; Gröger, Harald: An Asymmetric Organocatalytic Aldol Reaction of a Hydrophobic Aldehyde in Aqueous Medium Running in Flow Mode

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Gagosz, Fabien: Gold Vinylidenes as Useful Intermediates in Synthetic Organic Chemistry

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Zard, Samir Z.: Sulfur Betaines from S-Propargyl Xanthates. Unusual Chemistry from a Simple Functional Group

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Baldauf, Simon; Bode, Jeffrey W.: Synthesis and Evaluation of Cyclic Acetals of Serine Hydroxylamine for Amide-Forming KAHA Ligations

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Supporting Information

Leonov, Artem I.; Timofeeva, Daria S.; Ofial, Armin R.; Mayr, Herbert: Metal Enolates – Enamines – Enol Ethers: How Do Enolate Equivalents Differ in Nucleophilic Reactivity?

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Supporting Information

Crawford, Jennifer M.; Sigman, Matthew S.: Conformational Dynamics in Asymmetric Catalysis: Is Catalyst Flexibility a Design Element?

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Koeller, Julian; Gandeepan, Parthasarathy; Ackermann, Lutz: Visible-Light-Induced Decarboxylative C–H Adamantylation of Azoles at Ambient Temperature

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Supporting Information

Karlinskii, Bogdan Ya.; Romashov, Leonid V.; Galkin, Konstantin I.; Kislitsyn, Pavel G.; Ananikov, Valentine P.: Synthesis of 2-Azidomethyl-5-ethynylfuran: A New Bio-Derived Self-Clickable Building Block

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Supporting Information

Ueda, Mitsuhiro; Maeda, Ayami; Hamaoka, Kanako; Sasano, Mika; Fukuyama, Takahide; Ryu, Ilhyong: Bromine-Radical-Mediated Site-Selective Allylation of C(sp³)–H Bonds

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Supporting Information

Ferrer, Sofia; Echavarren, Antonio M.: Synthesis of Bullvalenes: Classical Approaches and Recent Developments

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McLellan, Ross; Uzelac, Marina; Bole, Leonie J.; Gil-Negrete, Jose María; Armstrong, David R.; Kennedy, Alan R.; Mulvey, Robert E.; Hevia, Eva: Alkali Metal Effects in Trans-Metal-Trapping (TMT): Comparing LiTMP with NaTMP in Cooperative MTMP/Ga(CH₂SiMe₃)₃ Metalation Reactions

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Supporting Information

Hu, Fan; Ng, Jerome P. L.; Chiu, Pauline: Pyrroles as Dienes in (4+3) Cycloadditions

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Dohi, Toshifumi; Sasa, Hirotaka; Dochi, Mio; Yasui, Chihiro; Kita, Yasuyuki: Oxidative Coupling of N-Methoxyamides and Related Compounds toward Aromatic Hydrocarbons by Designer μ-Oxo Hypervalent Iodine Catalyst

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Lanza, Francesco; Pérez, Juana M.; Jumde, Ravindra P.; Harutyunyan, Syuzanna R.: Lewis Acid Promoted Trapping of Chiral Aza-enolates

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Supporting Information

Wiegand, Anja; Wiese, Vera; Glowacki, Britta; Iovkova, Ljuba; Schirrmacher, Ralf; Jurkschat, Klaus; Krause, Norbert: GlucoSiFA and LactoSiFA: New Types of Carbohydrate-Tagged Silicon-Based Fluoride Acceptors for ¹⁸F-Positron Emission Tomography (PET)

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Supporting Information

Kurandina, Daria; Chuentragool, Padon; Gevorgyan, Vladimir: Transition-Metal-Catalyzed Alkyl Heck-Type Reactions

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Sun, Alexandra C.; McAtee, Rory C.; McClain, Edward J.; Stephenson, Corey R. J.: Advancements in Visible-Light-Enabled Radical C(sp)²–H Alkylation of (Hetero)arenes

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Cecchini, Chiara; Lanzi, Matteo; Cera, Gianpiero; Malacria, Max; Maestri, Giovanni: Complementary Reactivity of 1,6-Enynes with All-Metal Aromatic Trinuclear Complexes and Carboxylic Acids

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Supporting Information

Spránitz, Péter; Sőregi, Petra; Botlik, Bence Béla; Berta, Máté; Soós, Tibor: Organocatalytic Desymmetrisation of Fittig’s Lactones: Deuterium as a Reporter Tag for Hidden Racemisation

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Matsuoka, Seiya; Nakamura, Kayo; Ohmori, Ken; Suzuki, Keisuke: General Synthetic Approach to Rotenoids via Stereospecific, Group-Selective 1,2-Rearrangement and Dual S_NAr Cyclizations of Aryl Fluorides

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Supporting Information

Groso, Emilia J.; Schindler, Corinna S.: Recent Advances in the Application of Ring-Closing Metathesis for the Synthesis of Unsaturated Nitrogen Heterocycles

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Radtke, M. Alex; Dudley, Caroline C.; O’Leary, Jacob M.; Lambert, Tristan H.: A Scalable, One-Pot Synthesis of 1,2,3,4,5-Pentacarbomethoxycyclopentadiene

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Maraswami, Manikantha; Loh, Teck-Peng: Transition-Metal-Catalyzed Alkenyl sp² C–H Activation: A Short Account

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Blank, Lena; Fagnoni, Maurizio; Protti, Stefano; Rueping, Magnus: Visible Light-Promoted Formation of C–B and C–S Bonds under Metal- and Photocatalyst-Free Conditions

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Supporting Information

Blieck, Rémi; Perego, Luca Alessandro; Ciofini, Ilaria; Grimaud, Laurence; Taillefer, Marc; Monnier, Florian: Copper-Catalysed Hydroamination of N-Allenylsulfonamides: The Key Role of Ancillary Coordinating Groups

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Supporting Information

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Virtual Golden Anniversary Issue

50 Years SYNTHESIS