DOI: 10.1055/s-00000084

Synthesis

Ausgabe Golden_Issue · Volume · 2019 DOI: 10.1055/s-008-42090

Virtual Golden Anniversary Issue

50 Years SYNTHESIS

  • Paul, Knochel:

    50 Years SYNTHESIS – Golden Anniversary Issue

  • 50 Years SYNTHESIS – Golden Anniversary Issue Part II

  • Trost, Barry M.; Schultz, Johnathan E.:

    Palladium-Catalyzed Asymmetric Allylic Alkylation Strategies for the Synthesis of Acyclic Tetrasubstituted Stereocenters

    Image for article: Palladium-Catalyzed Asymmetric Allylic Alkylation Strategies for the Synthesis of Acyclic Tetrasubstituted Stereocenters
    Open Access
  • Grogg, Marcel; Hilvert, Donald; Beck, Albert K.; Seebach, Dieter:

    Syntheses of Cyanophycin Segments for Investigations of Cell-Penetration

    Image for article: Syntheses of Cyanophycin Segments for Investigations of Cell-Penetration
    Open Access
  • Murai, Masahito; Takai, Kazuhiko:

    Unsymmetrical Difunctionalization of Two Different C–H Bonds in One Pot Under Transition-Metal Catalysis

    Image for article: Unsymmetrical Difunctionalization of Two Different C–H Bonds in One Pot Under Transition-Metal Catalysis
    Open Access
  • Karageorgis, George; Waldmann, Herbert:

    Guided by Evolution: Biology-Oriented Synthesis of Bioactive Compound Classes

    Image for article: Guided by Evolution: Biology-Oriented Synthesis of Bioactive Compound Classes
    Open Access
  • Barrett, Anthony G. M.; Ma, Tsz-Kan; Mies, Thomas:

    Recent Developments in Polyene Cyclizations and Their Applications in Natural Product Synthesis

    Image for article: Recent Developments in Polyene Cyclizations and Their Applications in Natural Product Synthesis
    Open Access
  • Zhang, Heng; Lei, Aiwen:

    Electrochemical/Photochemical Aminations Based on Oxidative Cross-Coupling between C–H and N–H

    Image for article: Electrochemical/Photochemical Aminations Based on Oxidative Cross-Coupling between C–H and N–H
    Open Access
  • Piccardi, Riccardo; Turcaud, Serge; Benedetti, Erica; Micouin, Laurent:

    Synthesis and Reactivity of Mixed Dimethylalkynylaluminum Reagents

    Image for article: Synthesis and Reactivity of Mixed Dimethylalkynylaluminum Reagents
    Open Access
  • Kiefer, Alexander; Kazmaier, Uli:

    Syntheses of Cyclomarins – Interesting Marine Natural Products with Distinct Mode of Action towards Malaria and Tuberculosis

    Image for article: Syntheses of Cyclomarins – Interesting Marine Natural Products with Distinct Mode of Action towards Malaria and Tuberculosis
    Open Access
  • Wu, Xiang; Gong, Liu-Zhu:

    Palladium(0)-Catalyzed Difunctionalization of 1,3-Dienes: From Racemic to Enantioselective

    Image for article: Palladium(0)-Catalyzed Difunctionalization of 1,3-Dienes: From Racemic to Enantioselective
    Open Access
  • Yoshikai, Naohiko:

    Recent Advances in Enantioselective C–C Bond Formation via Organocobalt Species

    Image for article: Recent Advances in Enantioselective C–C Bond Formation via Organocobalt Species
    Open Access
  • Erb, William; Mongin, Florence:

    Twofold Ferrocene C–H Lithiations For One-Step Difunctionalizations

    Image for article: Twofold Ferrocene C–H Lithiations For One-Step Difunctionalizations
    Open Access
  • Lübken, Dennis; Saxarra, Marius; Kalesse, Markus:

    Tris(acetylacetonato) Iron(III): Recent Developments and Synthetic Applications

    Image for article: Tris(acetylacetonato) Iron(III): Recent Developments and Synthetic Applications
    Open Access
  • Barde, E.; Guérinot, A.; Cossy, J.:

    α-Arylation of Amides from α-Halo Amides Using Metal-Catalyzed Cross-Coupling Reactions

    Image for article: α-Arylation of Amides from α-Halo Amides Using Metal-Catalyzed Cross-Coupling Reactions
    Open Access
  • Kumagai, Naoya; Shibasaki, Masakatsu:

    7-Azaindoline Auxiliary: A Versatile Attachment Facilitating Enantioselective­ C–C Bond-Forming Catalysis

    Image for article: 7-Azaindoline Auxiliary: A Versatile Attachment Facilitating Enantioselective­ C–C Bond-Forming Catalysis
    Open Access
  • Stopka, Tobias; Adler, Pauline; Hagn, Gerhard; Zhang, Haoqi; Tona, Veronica; Maulide, Nuno:

    Electrophilic Activation of Amides for the Preparation of Poly­substituted Pyrimidines

    Image for article: Electrophilic Activation of Amides for the Preparation of Poly­substituted Pyrimidines
    Open Access
    Supporting Information (PDF)
  • Bartlett, Samuel L.; Keiter, Kimberly M.; Zavesky, Blane P.; Johnson, Jeffrey S.:

    Formation of Complex α-Imino Esters via Multihetero-Cope Rearrangement­ of α-Keto Ester Derived Nitrones

    Image for article: Formation of Complex α-Imino Esters via Multihetero-Cope Rearrangement­ of α-Keto Ester Derived Nitrones
    Open Access
    Supporting Information (PDF)
  • McCabe, Stephanie R.; Wipf, Peter:

    Asymmetric Total Synthesis and Biological Evaluation of (+)-Cycloclavine

    Image for article: Asymmetric Total Synthesis and Biological Evaluation of (+)-Cycloclavine
    Open Access
    Supporting Information (PDF)
  • Endoma-Arias, Mary Ann A.; Makarova, Mariia; Dela Paz, Helen E.; Hudlicky, Tomas:

    Chemoenzymatic Total Synthesis of (+)-Oxycodone from Phenethyl Acetate

    Image for article: Chemoenzymatic Total Synthesis of (+)-Oxycodone from Phenethyl Acetate
    Open Access
    Supporting Information (PDF)
  • Xue, Weichao; Oestreich, Martin:

    Silicon Grignard Reagents as Nucleophiles in Transition-Metal-Catalyzed Allylic Substitution

    Image for article: Silicon Grignard Reagents as Nucleophiles in Transition-Metal-Catalyzed Allylic Substitution
    Open Access
    Supporting Information (PDF)
  • Sato, Io; Yamashita, Yasuhiro; Kobayashi, Shū:

    Alkylpotassium-Catalyzed Benzylic C–H Alkylation of Alkylarenes with Alkenes

    Image for article: Alkylpotassium-Catalyzed Benzylic C–H Alkylation of Alkylarenes with Alkenes
    Open Access
    Supporting Information (PDF)
  • Nitelet, Antoine; Kairouz, Vanessa; Lebel, Hélène; Charette, André B.; Evano, Gwilherm:

    Continuous Flow Chlorination of Alkenyl Iodides Promoted by Copper Tubing

    Image for article: Continuous Flow Chlorination of Alkenyl Iodides Promoted by Copper Tubing
    Open Access
    Supporting Information (PDF)
  • Noguchi, Teppei; Nishii, Yuji; Miura, Masahiro:

    Rhodium-Catalyzed Cascade Annulative Coupling of 3,5-Diarylisoxazoles with Alkynes

    Image for article: Rhodium-Catalyzed Cascade Annulative Coupling of 3,5-Diarylisoxazoles with Alkynes
    Open Access
    Supporting Information (PDF)
  • Wang, Han; Zhang, Duo; Cao, Mengwei; Bolm, Carsten:

    Electrophilic Sulfoximidations of Thiols by Hypervalent Iodine Reagents

    Image for article: Electrophilic Sulfoximidations of Thiols by Hypervalent Iodine Reagents
    Open Access
    Supporting Information (PDF)
  • Gao, Wen-Chao; Xiong, Zi-Yue; Pirhaghani, Shafigh; Wirth, Thomas:

    Enantioselective Electrochemical Lactonization Using Chiral Iodoarenes as Mediators

    Image for article: Enantioselective Electrochemical Lactonization Using Chiral Iodoarenes as Mediators
    Open Access
    Supporting Information (PDF)
  • Konstantinova, Olga V.; Koskinen, Ari M.P.:

    Synthesis of the C1–C12 Fragment of Calyculin C

    Image for article: Synthesis of the C1–C12 Fragment of Calyculin C
    Open Access
    Supporting Information (PDF)
  • Bartolo, Nicole D.; Hornstein, Alana L.; Zhao, Annie Y.; Woerpel, K. A.:

    Diastereoselectivities in Reductions of α-Alkoxy Ketones Are Not Always Correlated to Chelation-Induced Rate Acceleration

    Image for article: Diastereoselectivities in Reductions of α-Alkoxy Ketones Are Not Always Correlated to Chelation-Induced Rate Acceleration
    Open Access
    Supporting Information (PDF)
  • Krieck, Sven; Schüler, Philipp; Peschel, Jan M.; Westerhausen, Matthias:

    Straightforward One-Pot Syntheses of Silylamides of Magnesium and Calcium via an In Situ Grignard Metalation Method

    Image for article: Straightforward One-Pot Syntheses of Silylamides of Magnesium and Calcium via an In Situ Grignard Metalation Method
    Open Access
    Supporting Information (PDF)
  • Stöckl, Yannick; Frey, Wolfgang; Lang, Johannes; Claasen, Birgit; Baro, Angelika; Laschat, Sabine:

    Asymmetric Organocatalysis Revisited: Taming Hydrindanes with Jørgensen–Hayashi Catalyst

    Image for article: Asymmetric Organocatalysis Revisited: Taming Hydrindanes with Jørgensen–Hayashi Catalyst
    Open Access
    Supporting Information (PDF)
  • Schober, Lukas; Ratnam, Shahilan; Yamashita, Yasunobu; Adebar, Niklas; Pieper, Matthias; Berkessel, Albrecht; Hessel, Volker; Gröger, Harald:

    An Asymmetric Organocatalytic Aldol Reaction of a Hydrophobic Aldehyde in Aqueous Medium Running in Flow Mode

    Image for article: An Asymmetric Organocatalytic Aldol Reaction of a Hydrophobic Aldehyde in Aqueous Medium Running in Flow Mode
    Open Access
  • Gagosz, Fabien:

    Gold Vinylidenes as Useful Intermediates in Synthetic Organic Chemistry

    Image for article: Gold Vinylidenes as Useful Intermediates in Synthetic Organic Chemistry
    Open Access
  • Zard, Samir Z.:

    Sulfur Betaines from S-Propargyl Xanthates. Unusual Chemistry from a Simple Functional Group

    Image for article: Sulfur Betaines from <i>S</i>-Propargyl Xanthates. Unusual Chemistry from a Simple Functional Group
    Open Access
  • Baldauf, Simon; Bode, Jeffrey W.:

    Synthesis and Evaluation of Cyclic Acetals of Serine Hydroxylamine for Amide-Forming KAHA Ligations

    Image for article: Synthesis and Evaluation of Cyclic Acetals of Serine Hydroxylamine for Amide-Forming KAHA Ligations
    Open Access
    Supporting Information (PDF)
  • Leonov, Artem I.; Timofeeva, Daria S.; Ofial, Armin R.; Mayr, Herbert:

    Metal Enolates – Enamines – Enol Ethers: How Do Enolate Equivalents Differ in Nucleophilic Reactivity?

    Image for article: Metal Enolates – Enamines – Enol Ethers: How Do Enolate Equivalents Differ in Nucleophilic Reactivity?
    Open Access
    Supporting Information (PDF)
  • Crawford, Jennifer M.; Sigman, Matthew S.:

    Conformational Dynamics in Asymmetric Catalysis: Is Catalyst Flexibility a Design Element?

    Image for article: Conformational Dynamics in Asymmetric Catalysis: Is Catalyst Flexibility a Design Element?
    Open Access
  • Koeller, Julian; Gandeepan, Parthasarathy; Ackermann, Lutz:

    Visible-Light-Induced Decarboxylative C–H Adamantylation of Azoles at Ambient Temperature

    Image for article: Visible-Light-Induced Decarboxylative C–H Adamantylation of Azoles at Ambient Temperature
    Open Access
    Supporting Information (PDF)
  • Karlinskii, Bogdan Ya.; Romashov, Leonid V.; Galkin, Konstantin I.; Kislitsyn, Pavel G.; Ananikov, Valentine P.:

    Synthesis of 2-Azidomethyl-5-ethynylfuran: A New Bio-Derived Self-Clickable Building Block

    Image for article: Synthesis of 2-Azidomethyl-5-ethynylfuran: A New Bio-Derived Self-Clickable Building Block
    Open Access
    Supporting Information (PDF)
  • Ueda, Mitsuhiro; Maeda, Ayami; Hamaoka, Kanako; Sasano, Mika; Fukuyama, Takahide; Ryu, Ilhyong:

    Bromine-Radical-Mediated Site-Selective Allylation of C(sp3)–H Bonds

    Image for article: Bromine-Radical-Mediated Site-Selective Allylation of C(sp<sup>3</sup>)–H Bonds
    Open Access
    Supporting Information (PDF)
  • Ferrer, Sofia; Echavarren, Antonio M.:

    Synthesis of Bullvalenes: Classical Approaches and Recent Developments

    Image for article: Synthesis of Bullvalenes: Classical Approaches and Recent Developments
    Open Access
  • McLellan, Ross; Uzelac, Marina; Bole, Leonie J.; Gil-Negrete, Jose María; Armstrong, David R.; Kennedy, Alan R.; Mulvey, Robert E.; Hevia, Eva:

    Alkali Metal Effects in Trans-Metal-Trapping (TMT): Comparing LiTMP with NaTMP in Cooperative MTMP/Ga(CH2SiMe3)3 Meta­lation Reactions

    Image for article: Alkali Metal Effects in Trans-Metal-Trapping (TMT): Comparing LiTMP with NaTMP in Cooperative MTMP/Ga(CH<sub>2</sub>SiMe<sub>3</sub>)<sub>3</sub> Meta­lation Reactions
    Open Access
    Supporting Information (PDF)
  • Hu, Fan; Ng, Jerome P. L.; Chiu, Pauline:

    Pyrroles as Dienes in (4+3) Cycloadditions

    Image for article: Pyrroles as Dienes in (4+3) Cycloadditions
    Open Access
  • Dohi, Toshifumi; Sasa, Hirotaka; Dochi, Mio; Yasui, Chihiro; Kita, Yasuyuki:

    Oxidative Coupling of N-Methoxyamides and Related Compounds toward Aromatic Hydrocarbons by Designer μ-Oxo Hypervalent Iodine Catalyst

    Image for article: Oxidative Coupling of <i>N</i>-Methoxyamides and Related Compounds toward Aromatic Hydrocarbons by Designer μ-Oxo Hypervalent Iodine Catalyst
    Open Access
  • Lanza, Francesco; Pérez, Juana M.; Jumde, Ravindra P.; Harutyunyan, Syuzanna R.:

    Lewis Acid Promoted Trapping of Chiral Aza-enolates

    Image for article: Lewis Acid Promoted Trapping of Chiral Aza-enolates
    Open Access
    Supporting Information (PDF)
  • Wiegand, Anja; Wiese, Vera; Glowacki, Britta; Iovkova, Ljuba; Schirrmacher, Ralf; Jurkschat, Klaus; Krause, Norbert:

    GlucoSiFA and LactoSiFA: New Types of Carbohydrate-Tagged Silicon-Based Fluoride Acceptors for 18F-Positron Emission Tomography (PET)

    Image for article: GlucoSiFA and LactoSiFA: New Types of Carbohydrate-Tagged Silicon-Based Fluoride Acceptors for <sup>18</sup>F-Positron Emission Tomography (PET)
    Open Access
    Supporting Information (PDF)
  • Kurandina, Daria; Chuentragool, Padon; Gevorgyan, Vladimir:

    Transition-Metal-Catalyzed Alkyl Heck-Type Reactions

    Image for article: Transition-Metal-Catalyzed Alkyl Heck-Type Reactions
    Open Access
  • Sun, Alexandra C.; McAtee, Rory C.; McClain, Edward J.; Stephenson, Corey R. J.:

    Advancements in Visible-Light-Enabled Radical C(sp)2–H Alkylation of (Hetero)arenes

    Image for article: Advancements in Visible-Light-Enabled Radical C(sp)<sup>2</sup>–H Alkylation of (Hetero)arenes
    Open Access
  • Cecchini, Chiara; Lanzi, Matteo; Cera, Gianpiero; Malacria, Max; Maestri, Giovanni:

    Complementary Reactivity of 1,6-Enynes with All-Metal Aromatic Trinuclear Complexes and Carboxylic Acids

    Image for article: Complementary Reactivity of 1,6-Enynes with All-Metal Aromatic Trinuclear Complexes and Carboxylic Acids
    Open Access
    Supporting Information (PDF)
  • Spránitz, Péter; Sőregi, Petra; Botlik, Bence Béla; Berta, Máté; Soós, Tibor:

    Organocatalytic Desymmetrisation of Fittig’s Lactones: Deuterium as a Reporter Tag for Hidden Racemisation

    Image for article: Organocatalytic Desymmetrisation of Fittig’s Lactones: Deuterium as a Reporter Tag for Hidden Racemisation
    Open Access
  • Matsuoka, Seiya; Nakamura, Kayo; Ohmori, Ken; Suzuki, Keisuke:

    General Synthetic Approach to Rotenoids via Stereospecific, Group-Selective 1,2-Rearrangement and Dual SNAr Cyclizations of Aryl Fluorides

    Image for article: General Synthetic Approach to Rotenoids via Stereospecific, Group-Selective 1,2-Rearrangement and Dual S<sub>N</sub>Ar Cyclizations of Aryl Fluorides
    Open Access
    Supporting Information (PDF)
  • Groso, Emilia J.; Schindler, Corinna S.:

    Recent Advances in the Application of Ring-Closing Metathesis for the Synthesis of Unsaturated Nitrogen Heterocycles

    Image for article: Recent Advances in the Application of Ring-Closing Metathesis for the Synthesis of Unsaturated Nitrogen Heterocycles
    Open Access
  • Radtke, M. Alex; Dudley, Caroline C.; O’Leary, Jacob M.; Lambert, Tristan H.:

    A Scalable, One-Pot Synthesis of 1,2,3,4,5-Pentacarbomethoxycyclopentadiene

    Image for article: A Scalable, One-Pot Synthesis of 1,2,3,4,5-Pentacarbomethoxycyclopentadiene
    Open Access
  • Maraswami, Manikantha; Loh, Teck-Peng:

    Transition-Metal-Catalyzed Alkenyl sp2 C–H Activation: A Short Account

    Image for article: Transition-Metal-Catalyzed Alkenyl sp<sup>2</sup> C–H Activation: A Short Account
    Open Access
  • Blank, Lena; Fagnoni, Maurizio; Protti, Stefano; Rueping, Magnus:

    Visible Light-Promoted Formation of C–B and C–S Bonds under Metal- and Photocatalyst-Free Conditions

    Image for article: Visible Light-Promoted Formation of C–B and C–S Bonds under Metal- and Photocatalyst-Free Conditions
    Open Access
    Supporting Information (PDF)
  • Blieck, Rémi; Perego, Luca Alessandro; Ciofini, Ilaria; Grimaud, Laurence; Taillefer, Marc; Monnier, Florian:

    Copper-Catalysed Hydroamination of N-Allenylsulfonamides: The Key Role of Ancillary Coordinating Groups

    Image for article: Copper-Catalysed Hydroamination of <i>N</i>-Allenylsulfonamides: The Key Role of Ancillary Coordinating Groups
    Open Access
    Supporting Information (PDF)