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Synthesis 2023; 55(18): 3033-3039
DOI: 10.1055/a-2006-1285
DOI: 10.1055/a-2006-1285
paper
Special Issue Electrochemical Organic Synthesis
Electrochemical Synthesis of trans-Olefins from Buta-1,3-dienes and Alkyl Halides
We are grateful for the financial support from the Science and Technology Planning Project of Shenzhen Municipality (No. JCYJ20210324133001004 and JCYJ20210324132803009), the Natural Science Foundation of Guangdong Province (No. 2020A1515010564), and Basic and Applied Basic Research Foundation of Guangdong Province (No. 2021A1515220069). W.X. is grateful for the Guangdong Pearl River Talents Program and the financial support from Guangdong Province Covid-19 Pandemic Control Research Fund (No. 2020KZDZX1218). The project was also supported by State Key Laboratory of Urban Water Resource and Environment (Harbin Institute of Technology) (No.2022TS24), and the Open Research Fund of the School of Chemistry and Chemical Engineering, Henan Normal University.
Abstract
A facile electrochemical alkylation reaction of buta-1,3-diene derivatives with alkyl halides has been developed, generating highly selective trans-olefins as major products. This method exhibits significant advantages, including simple operation, mild conditions, and convenience of scale-up, and provides a novel route for the synthesis of trans-olefins.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-2006-1285.
- Supporting Information
Publication History
Received: 30 November 2022
Accepted after revision: 03 January 2023
Accepted Manuscript online:
03 January 2023
Article published online:
01 February 2023
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