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Synthesis 2024; 56(16): 2565-2571
DOI: 10.1055/a-2315-1934
DOI: 10.1055/a-2315-1934
paper
Photocatalytic Annulation of Enaminones with Thioureas for the Synthesis of 2-Aminothiazoles via Tandem C–S and C–N Bond Formation
The authors thank the National Natural Science Foundation of China (Grant: 22161022) for funding.
Abstract
Visible-light photocatalytic reactions between enaminones and thioureas leading to thiazole products have been achieved. The annulation process consists of tandem C–S and C–N bond formation by running reactions under air atmosphere at ambient temperature. Broad substrate tolerance of the sustainable protocol has been verified by the practical synthesis of divergent thiazoles with both monocyclic and fused cyclic structures.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-2315-1934.
- Supporting Information
Publication History
Received: 01 April 2024
Accepted after revision: 26 April 2024
Accepted Manuscript online:
26 April 2024
Article published online:
15 May 2024
© 2024. Thieme. All rights reserved
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