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Synthesis 2024; 56(13): 2031-2046
DOI: 10.1055/a-2326-6277
DOI: 10.1055/a-2326-6277
paper
Palladium Nano-Dispersed and Stabilized in Organically Modified Silicate as a Heterogeneous Catalyst for the Conversion of Aldehydes into O-Silyl Ether Derivatives under Neat Conditions
J.F. acknowledges the financial support from the National Science Foundation (NSF CHE-1954734) and from the Edward G. Schlieder Educational Foundation.
Abstract
Palladium nanoparticles are dispersed and stabilized in organically modified silicate (Pd@MTES), and characterized by a number of spectroscopic techniques, including FTIR, TEM, SEM, and XPS. The catalytic effect of this material toward the hydrosilylation of aldehydes and ketones is explored, and the scope of the reaction investigated, with 26 examples provided. This reaction proceeds under neat conditions via heterogeneous catalysis, and a mechanistic pathway supported by DFT calculations is proposed.
Key words
palladium nanoparticles - hydrosilylation - aldehydes - ketones - heterogeneous catalysis - DFT calculationsSupporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-2326-6277.
- Supporting Information
Publication History
Received: 02 April 2024
Accepted after revision: 14 May 2024
Accepted Manuscript online:
14 May 2024
Article published online:
04 June 2024
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