Synthesis 2017; 49(06): 1223-1230
DOI: 10.1055/s-0036-1588652
paper
© Georg Thieme Verlag Stuttgart · New York

Chan–Lam-Type C–N Cross-Coupling Reactions under Base- and Ligand-Free CuI-Zeolite Catalysis

Tony Garnier
a   Institut des Technologies Avancées en sciences du Vivant (ITAV), Université de Toulouse, CNRS, UPS, 1 place Pierre Potier, 31106 Toulouse Cedex 1, France
,
Randa Sakly
a   Institut des Technologies Avancées en sciences du Vivant (ITAV), Université de Toulouse, CNRS, UPS, 1 place Pierre Potier, 31106 Toulouse Cedex 1, France
b   Laboratoire de Chimie Organique Hétérocyclique, Produits Naturels et Réactivité (LCOHPNR), Faculté des Sciences de Monastir, Université de Monastir, Monastir, Tunisie
,
Mathieu Danel
a   Institut des Technologies Avancées en sciences du Vivant (ITAV), Université de Toulouse, CNRS, UPS, 1 place Pierre Potier, 31106 Toulouse Cedex 1, France
,
Stefan Chassaing*
a   Institut des Technologies Avancées en sciences du Vivant (ITAV), Université de Toulouse, CNRS, UPS, 1 place Pierre Potier, 31106 Toulouse Cedex 1, France
,
Patrick Pale*
c   Laboratoire de Synthèse, Réactivité Organique et Catalyse (LASYROC), Institut de Chimie, CNRS-UMR7177, Université de Strasbourg, 4 rue Blaise Pascal, 67070 Strasbourg, France   Email: stefan.chassaing@itav.fr   Email: ppale@unistra.fr
› Author Affiliations
Further Information

Publication History

Received: 14 September 2016

Accepted: 20 October 2016

Publication Date:
22 November 2016 (online)


Dedicated to the memory of Prof. J. F. Normant, a brilliant scientist and a wonderful person, and in recognition of his outstanding achievements in organometallic chemistry.

Abstract

Various representative copper(I)-exchanged zeolites were investigated for their catalytic potential in Chan–Lam cross-coupling reactions. CuI-USY appeared as the best catalyst and proved to efficiently promote C–N cross-coupling processes under attractive, simple, and practical conditions, namely refluxing in methanol under air and without any base.

Supporting Information

 
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