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CC BY-ND-NC 4.0 · Synthesis 2019; 51(01): 135-145
DOI: 10.1055/s-0037-1610397
DOI: 10.1055/s-0037-1610397
short review
Recent Advances in Enantioselective C–C Bond Formation via Organocobalt Species
Ministry of Education Singapore (MOE2016-T2-2-043)Further Information
Publication History
Received: 27 October 2018
Accepted: 05 November 2018
Publication Date:
03 December 2018 (online)


Published as part of the 50 Years SYNTHESIS – Golden Anniversary Issue
Abstract
This Short Review describes recent developments in cobalt-catalyzed enantioselective C–C bond-forming reactions. The article focuses on reactions that most likely involve chiral organocobalt species as crucial catalytic intermediates and their mechanistic aspects.
1 Introduction
2 Hydrovinylation
3 C–H Functionalization
4 Cycloaddition and Cyclization
5 Addition of Carbon Nucleophiles
6 Cross-Coupling
7 Conclusion