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Synlett 1995; 1995(1): 43-45
DOI: 10.1055/s-1995-4861
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Iminophosphorane-Mediated Synthesis of the Carbon Skeleton of the Azafluoranthene Alkaloids Rufescine and Imeluteine

Pedro Molina* , Sagrario Garcia-Zafra, Pilar M. Fresneda
  • *Departamento de Química Orgánica, Facultad de Química, Universidad de Murcia, Campus de Espinardo, E-30071, Murcia, Spain
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Publication Date:
31 December 2000 (online)

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A new four-step synthesis of the carbon skeleton of the azafluoranthene alkaloids rufescine and imeluteine based on a combitational aza Wittig/electrocyclic ring closure-intramolecular oxidative biaryl coupling is described.

azafluoranthene alkaloids - aza Wittig/electrocyclic ring-closure - oxidative biaryl coupling - rufescine - imeluteine