Download PDF
Synlett 1995; 1995(12): 1229-1231
DOI: 10.1055/s-1995-5253
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Diastereoselective Reduction of α-(p-Tolylsulfinyl)ketoximes

Kazuyuki Miyashita, Tomohiro Toyoda, Hideto Miyabe, Takeshi Imanishi*
  • *Faculty of Pharmaceutical Sciences, Osaka University, 1-6 Yamadaoka, Suita, Osaka 565, Japan
Further Information

Publication History

Publication Date:
31 December 2000 (online)

 PDF Download  Permissions and Reprints All articles of this category

α-Sulfinylketoximes were stereoselectively reduced by L-Selectride to give (S)-(N-methoxyamino)sulfoxides, which is the first successful example for diastereoselective reduction of α-sulfinylimino derivatives via a ”nonchelate model”.

α-(p-tolylsulfinyl)ketoxime - diastereoselective reduction - L-Selectride - nonchelate model - optically active amine