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Synlett 2023; 34(20): 2361-2373
DOI: 10.1055/a-2124-4037
DOI: 10.1055/a-2124-4037
account
Special Issue Dedicated to Prof. Hisashi Yamamoto
Metal-Loaded Semiconductor-Photocatalysis of Alcohols for Selective Organic Synthesis: A Personal Account
This work was supported by MEXT/JSPS Grant-in-aid for Transformative Research Areas (A) Green Catalysis Science, Specially Promoted Research, and International Leading Research, KAKENHI (Grant # 23H04904, 23H05404, and 22K21346 to S.S.), and partially by JST CREST (Grant # JPMJCR22L2 to S.S.), MEXT Grant in aid-for transformative research areas (B): Deuterium Science, KAKENHI (Grant # 20H05740, to H.N.), and JSPS KAKENHI (Grant # 26410115 and 23H01958, to H.N.).
Dedicated to Professor Hisashi Yamamoto on the occasion of his 80th birthday
Abstract
In this account, we review our research over the last decade on metal-loaded semiconductor-photocatalyzed organic transformations using alcohols. Different from many reactions using alcohols as mere sacrificial electron donors, our study has demonstrated alcohols as useful organic building blocks incorporated into value-added products. Besides such recollections of previous results, we briefly introduce our ongoing project involving photocatalytic C–C bond-forming reactions via the C–C bond scission of tertiary alcohols.
1 Introduction
2 Dehydroxylative Hydrogenolysis of Allylic Alcohols
3 Acceptorless Dehydrogenation of Activated/Unactivated Alcohols
4 N-Alkylation of Amines using Alcohols as Alkylating Agents
5 Summary and Outlook
Key words
semiconductors - photocatalysts - alcohols - dehydroxylative hydrogenolysis - dehydrogenation - N-alkylation - N-methylation - β-scissionPublication History
Received: 21 June 2023
Accepted after revision: 06 July 2023
Accepted Manuscript online:
06 July 2023
Article published online:
25 August 2023
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