Stereo- and Site-Selective Acylation in Carbohydrate Synthesis

Stephanie A. Blaszczyk; Xiaolei Li; Peng Wen; Weiping Tang

doi:10.1055/a-2214-7557

Synlett, Table of Contents

Synlett 2024; 35(15): 1745-1762
DOI: 10.1055/a-2214-7557

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Stereo- and Site-Selective Acylation in Carbohydrate Synthesis

Authors

Stephanie A. Blaszczyk

^aSchool of Pharmacy, University of Wisconsin-Madison, 777 Highland Ave, Madison, WI 53705, USA

^bDepartment of Chemistry, University of Wisconsin-Madison, 1101 University Ave, Madison, WI 53706, USA
Xiaolei Li

^aSchool of Pharmacy, University of Wisconsin-Madison, 777 Highland Ave, Madison, WI 53705, USA
Peng Wen

^aSchool of Pharmacy, University of Wisconsin-Madison, 777 Highland Ave, Madison, WI 53705, USA
Weiping Tang∗

^aSchool of Pharmacy, University of Wisconsin-Madison, 777 Highland Ave, Madison, WI 53705, USA

^bDepartment of Chemistry, University of Wisconsin-Madison, 1101 University Ave, Madison, WI 53706, USA

Abstract

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Abstract

Carbohydrates are synthetically challenging molecules with vital biological roles in all living systems. To better understand the biological functions of this fundamentally important class of molecules, novel methodologies are needed, including site-selective functionalization and glycosylation reactions. This account describes our efforts toward the development of novel methodologies for site-selective functionalization of carbohydrates and stereoselective glycosylation through various acylation reactions.

Keywords

carbohydrate - esterification - catalysis - site-selective functionalization - stereoselective

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References

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