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DOI: 10.1055/a-2529-7304
Toward a Greener Tomorrow: Sustainable Synthesis of Well-defined Polymers in Ionic Liquids via Recyclable Nanocatalyst-Mediated Photopolymerization
Funding Information The research was funded by a grant received from DRDO, Government of India (ERIP/ER/202311001/M/01/1850).
Abstract
The widespread use of ionic liquids (ILs) in reversible deactivation radical polymerization (RDRP) procedures has opened new pathways to address the problems caused by hazardous solvents. Additionally, photoinduced RDRP (photoRDRP) of methacrylate monomers in recyclable ILs has been developed, which is catalyzed by magnetic nano zero-valent iron (nZVI), enabling incredible control over M n and Đ s during the polymerization of methyl methacrylate (MMA) by simply turning the UVA radiation (λ max ≈ 352 nm) “ON” and “OFF”. This allows for good temporal control. Furthermore, the chain end fidelity was determined through the synthesis of many distinct diblock copolymers with acceptable Đ s values (≤1.20).
Keywords
Recyclable ionic liquid - Nano zero-valent iron - PhotoRDRP - Diblock copolymer - Sustainable methodSupplementary Material
- Supplementary Material is available at https://doi.org/10.1055/a-2529-7304.
- Supporting Information
Publication History
Received: 06 October 2024
Accepted after revision: 28 January 2025
Accepted Manuscript online:
30 January 2025
Article published online:
17 April 2025
© 2025. The Author(s). This is an open access article published by Thieme under the terms of the Creative Commons Attribution License, permitting unrestricted use, distribution, and reproduction so long as the original work is properly cited. (https://creativecommons.org/licenses/by/4.0/).
Georg Thieme Verlag KG
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Amul Jain, Bhanendra Sahu, Nikhil Ingale, Sanjib Banerjee. Toward a Greener Tomorrow: Sustainable Synthesis of Well-defined Polymers in Ionic Liquids via Recyclable Nanocatalyst-Mediated Photopolymerization. Sustainability & Circularity NOW 2025; 02: a25297304.
DOI: 10.1055/a-2529-7304
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References
- 1 Alni A, Cahya AY, Wahyuningrum DJ. K. E. M. KEM 2019; 811: 86-91
- 2 Welton T. J. Chem. Rev. 1999; 99 (08) 2071-2084
- 3 Choi H.-J, Selvaraj M, Park D.-W. Chem. Eng. Sci. 2013; 100: 242-248
- 4 Dai C, Zhang J, Huang C, Lei Z. Chem. Rev. 2017; 117 (10) 6929-6983
- 5 Yang H, Liu Y, Ning H, Lei J, Hu G. RSC Adv. 2017; 7 (53) 33231-33240
- 6 Hallett JP, Welton T. Chem. Rev. 2011; 111 (05) 3508-3576
- 7 Singh A, Kumar Chopra H. Curr. Org. Synth. 2017; 14 (04) 488-510
- 8 Skoda-Földes R. Molecules 2014; 19 (07) 8840-8884
- 9 Cabral DM, Howlett PC, MacFarlane DR. Electrochim. Acta 2016; 220: 347-353
- 10 Pandey S. Anal. Chim. Acta 2006; 556 (01) 38-45
- 11 Wang R, Gao H, Ye C, Shreeve JN. M. Chem. Mater. 2007; 19 (02) 144-152
- 12 Corrigan N, Jung K, Moad G, Hawker CJ, Matyjaszewski K, Boyer C. Prog. Polym. Sci. 2020; 111: 101311
- 13 Stuart MA. C, Huck WT, Genzer J, Müller M, Ober C, Stamm M, Sukhorukov GB, Szleifer I, Tsukruk VV, Urban M. Nat. Mater 2010; 9 (02) 101-113
- 14 Wei M, Gao Y, Li X, Serpe MJ. Polym. Chem. 2017; 8 (01) 127-143
- 15 Ouchi M, Badi N, Lutz J.-F, Sawamoto M. Nat. Chem. 2011; 3 (12) 917-924
- 16 Matyjaszewski K. J. Macromol. 2012; 45 (10) 4015-4039
- 17 Lligadas G, Grama S, Percec V. J. Biol. Macromol. 2017; 18 (10) 2981-3008
- 18 Nicolas J, Guillaneuf Y, Lefay C, Bertin D, Gigmes D, Charleux B. Prog. Polym. Sci. 2013; 38 (01) 63-235
- 19 Hill MR, Carmean RN, Sumerlin BS. J Macromol. 2015; 48 (16) 5459-5469
- 20 Morin AN, Detrembleur C, Jérôme C, De Tullio P, Poli R, Debuigne A. J. Macromol. 2013; 46 (11) 4303-4312
- 21 Wang W, Zhao J, Zhou N, Zhu J, Zhang W, Pan X, Zhang Z, Zhu X. Polym. Chem. 2014; 5 (11) 3533-3546
- 22 Zhou H, Zhang L, Wen P, Zhou Y, Zhao Y, Zhao Q, Gu Y, Bai R, Chen M. Angew. Chem. 2023; 135 (27) e202304461
- 23 Tian C, Wang P, Ni Y, Zhang L, Cheng Z, Zhu X. Angew. Chem., Int. Ed. 2020; 59 (10) 3910-3916
- 24 Bagheri A, Jin J. ACS Appl. Polym. Mater. 2019; 1 (04) 593-611
- 25 Magenau AJ, Strandwitz NC, Gennaro A, Matyjaszewski K. J. Sci. 2011; 332 (6025) 81-84
- 26 Rzayev J, Penelle J. Angew. Chem., Int. Ed. 2004; 116 (13) 1723-1726
- 27 Dworakowska S, Lorandi F, Gorczyński A, Matyjaszewski K. J. Adv. Sci. 2022; 9 (19) 2106076
- 28 Dadashi-Silab S, Pan X, Matyjaszewski K. J. Macromol. 2017; 50 (20) 7967-7977
- 29 Boyer C, Corrigan NA, Jung K, Nguyen D, Nguyen T.-K, Adnan NN. M, Oliver S, Shanmugam S, Yeow J. Chem. Rev. 2016; 116 (04) 1803-1949
- 30 Wang Y. J. Polym. 2019; 11 (08) 1238
- 31 Parkatzidis K, de Haro Amez L, Truong NP, Anastasaki A. J. Polym. Chem. 2023; 14 (14) 1639-1645
- 32 Egorova KS, Gordeev EG, Ananikov VP. Chem. Rev. 2017; 117 (10) 7132-7189
- 33 Sahu B, Sinha P, Kumar D, Patel K, Banerjee S. Macromol. Rapid Commun. 2024; 45 (03) 2300500
- 34 Kumar D, Sahu B, Dolui S, Rajput SS, Alam MM, Banerjee S. Eur. Polym. J. 2023; 199: 112443
- 35 Dinda E, Si S, Kotal A, Mandal TK. J. C. A. E. J. Chem. – Eur. J. 2008; 14 (18) 5528-5537
- 36 Sahu B, Sinha P, Mishra B, Tripathi BP, Banerjee S. ACS Appl. Polym. Mater.. 2024
- 37 Flores JD, Treat NJ, York AW, McCormick CL. Polym. Chem. 2011; 2 (09) 1976-1985
- 38 Heatley F, Bovey F. Macromolecules 1969; 2 (03) 241-245
- 39 Karabelli D, Üzüm CA. R, Shahwan T, Eroglu AE, Scott TB, Hallam KR, Lieberwirth IJ. I, Research EC. Ind. Eng. Chem. Res. 2008; 47 (14) 4758-4764