Photoinduced Deaminative C(sp3)–H Bond diarylation of glycine derivatives by cerium catalysis

Shutao Wang; Jinyi Liao; Yukang Li; Yuan Zhang; Li-Na Guo

doi:10.1055/a-2705-4304

Synthesis, Inhaltsverzeichnis

Synthesis
DOI: 10.1055/a-2705-4304

Paper

Published as part of the Special Topic Dedicated to Prof. Paul Knochel

Photoinduced Deaminative C(sp³)–H Bond diarylation of glycine derivatives by cerium catalysis

Authors

Shutao Wang

¹Department of Chemistry, School of Chemistry, Xi’an Key Laboratory of Sustainable Energy Material Chemistry and Engineering Research Center of Energy Storage, Materials and Devices, Ministry of Education, Xi’an Jiaotong University, Xi’an, China
Jinyi Liao

¹Department of Chemistry, School of Chemistry, Xi’an Key Laboratory of Sustainable Energy Material Chemistry and Engineering Research Center of Energy Storage, Materials and Devices, Ministry of Education, Xi’an Jiaotong University, Xi’an, China
Yukang Li

¹Department of Chemistry, School of Chemistry, Xi’an Key Laboratory of Sustainable Energy Material Chemistry and Engineering Research Center of Energy Storage, Materials and Devices, Ministry of Education, Xi’an Jiaotong University, Xi’an, China
Yuan Zhang

²State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou, China
Li-Na Guo

¹Department of Chemistry, School of Chemistry, Xi’an Key Laboratory of Sustainable Energy Material Chemistry and Engineering Research Center of Energy Storage, Materials and Devices, Ministry of Education, Xi’an Jiaotong University, Xi’an, China

Abstract

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Abstract

A Ce(III)-catalyzed, visible light–induced aerobic oxidative diarylation of glycine derivatives with electron-rich aromatics is described. This method enables the efficient and rapid synthesis of diarylmethane derivatives under mild conditions, using air as the oxidant and obviating the need for an external photosensitizer. It is noteworthy that this protocol can be scaled up to 5 mmol without a significant impact on the efficiency.

Keywords

Glycine derivative - Visible-light induced - Photosensitizers free - Diarylation - Cerium catalysis

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