Synlett 2012; 23(10): 1549-1553
DOI: 10.1055/s-0031-1290935
letter
© Georg Thieme Verlag Stuttgart · New York

Magnetically Separable Cu-Carboxylate MOF Catalyst for the Henry Reaction

Takayoshi Arai*
Department of Chemistry, Graduate School of Science, Chiba University, Inage, Chiba 263-8522, Japan, Fax: +81(43)2902889   Email: tarai@faculty.chiba-u.jp
,
Nao Kawasaki
Department of Chemistry, Graduate School of Science, Chiba University, Inage, Chiba 263-8522, Japan, Fax: +81(43)2902889   Email: tarai@faculty.chiba-u.jp
,
Hirofumi Kanoh
Department of Chemistry, Graduate School of Science, Chiba University, Inage, Chiba 263-8522, Japan, Fax: +81(43)2902889   Email: tarai@faculty.chiba-u.jp
› Author Affiliations
Further Information

Publication History

Received: 24 January 2012

Accepted after revision: 09 March 2012

Publication Date:
24 May 2012 (online)


Abstract

An air-stable Cu-carboxylate MOF complex can catalyze the cross-coupling reaction of phenylacetylene with 2-oxazolidone and Henry reaction. The Cu-carboxylate MOF encapsulated magnetic beads (MOF-MB II) was also prepared. The MOF-MB II was successfully reused in the Henry reaction by a simple magnetic separation.

 
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