Study of Ring-Opening Reaction of Spiro[5.2]octenes with Aqueous Hydro­halic Acid: Substituent Effect on the Regioselectivity

Abstract

We describe here the regioselective ring-opening reaction of spiro[5.2]octenes with hydrohalic acids. It was observed that the electronic nature of a substituent on the cyclopropane ring would control the regioselectivity.

Key words

alkenylcyclopropanes - electrophilic addition - regio­selectivity - ring opening - spiro compound

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