Comparing Well-Defined Manganese, Iron, Cobalt, and Nickel Ketone Hydrosilylation Catalysts

Ryan J. Trovitch

doi:10.1055/s-0033-1341269

Synlett, Table of Contents

Synlett 2014; 25(12): 1638-1642
DOI: 10.1055/s-0033-1341269

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Comparing Well-Defined Manganese, Iron, Cobalt, and Nickel Ketone Hydrosilylation Catalysts

Ryan J. Trovitch*

Department of Chemistry & Biochemistry, Arizona State University, Tempe, AZ 85287, USA Fax: +1(480)9652747 Email: ryan.trovitch@asu.edu

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Abstract

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Abstract

A brief review of manganese-catalyzed hydrosilylation is presented along with a personal account of how the design for the highly active catalyst, (^Ph2PPrPDI)Mn, was conceived. The reductive transformations achieved using this catalyst are described and put into further context by comparing the observed activities with those attained for leading late first-row transition-metal catalysts.

Key words

catalysis - hydrosilylation - ketones - manganese - ligands

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References

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