Selective Azidation of Aryl Halides to Aryl Azides Promoted by Proline and CuFeO2

Abdol Reza Hajipour; Morteza Karimzadeh; Sirous Ghorbani

doi:10.1055/s-0034-1378903

Synlett, Table of Contents

Synlett 2014; 25(20): 2903-2907
DOI: 10.1055/s-0034-1378903

letter

Selective Azidation of Aryl Halides to Aryl Azides Promoted by Proline and CuFeO₂

Authors

Abdol Reza Hajipour*

^aPharmaceutical Research Laboratory, Department of Chemistry, Isfahan University of Technology, Isfahan 84156, Iran Fax: +98(311)3912350 Email: haji@cc.iut.ac.ir

^bDepartment of Neuroscience, University of Wisconsin, Medical School, 1300 University Avenue, Madison, WI 53706-1532, USA
Morteza Karimzadeh

^aPharmaceutical Research Laboratory, Department of Chemistry, Isfahan University of Technology, Isfahan 84156, Iran Fax: +98(311)3912350 Email: haji@cc.iut.ac.ir
Sirous Ghorbani

Abstract

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Abstract

An efficient and selective azidation of aryl halides by reacting sodium azide with aryl halides is described. The heterogeneous nature of the copper(Ι) catalyst, which catalyzes the cross-coupling reactions, and the antiviral and antibacterial properties of the products are features of this methodology. It is also worth noting that no aryl amines are produced as byproducts under these conditions.

Key words

aryl azides - l-proline - delafossite - heterogeneous catalysis

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References

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Supplementary Material

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