Synlett 2014; 25(19): 2757-2760
DOI: 10.1055/s-0034-1379211
letter
© Georg Thieme Verlag Stuttgart · New York

Microwave-Assisted Oxidation of Alcohols Using Zinc Polyoxometalate

Wiktor Kasprzyk*
Department of Biotechnology and Physical Chemistry, Faculty of Chemical Engineering and Technology, Cracow University of Technology, Warszawska 24 St., 31-155 Krakow, Poland   Fax: +48(12)6342425   Email: jumper.wk@gmail.com
,
Mateusz Galica
Department of Biotechnology and Physical Chemistry, Faculty of Chemical Engineering and Technology, Cracow University of Technology, Warszawska 24 St., 31-155 Krakow, Poland   Fax: +48(12)6342425   Email: jumper.wk@gmail.com
,
Szczepan Bednarz
Department of Biotechnology and Physical Chemistry, Faculty of Chemical Engineering and Technology, Cracow University of Technology, Warszawska 24 St., 31-155 Krakow, Poland   Fax: +48(12)6342425   Email: jumper.wk@gmail.com
,
Dariusz Bogdał
Department of Biotechnology and Physical Chemistry, Faculty of Chemical Engineering and Technology, Cracow University of Technology, Warszawska 24 St., 31-155 Krakow, Poland   Fax: +48(12)6342425   Email: jumper.wk@gmail.com
› Author Affiliations
Further Information

Publication History

Received: 16 July 2014

Accepted after revision: 01 September 2014

Publication Date:
07 October 2014 (online)


Abstract

In the presence of 30% aqueous hydrogen peroxide and [WZn3(H2O)2][ZnW9O34)2]12– polyoxometalate as a catalyst, primary and secondary alcohols were oxidized to carboxylic acids and ketones, respectively, in short reaction times (ca. 15 min) under microwave-pressurized conditions.

Supporting Information

 
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