Synlett
DOI: 10.1055/s-0036-1590891
letter
© Georg Thieme Verlag Stuttgart · New York

Iron-Catalyzed C(sp2)–C(sp3) Cross-Coupling Reactions of Di(hetero)arylmanganese Reagents and Primary and Secondary Alkyl Halides

Maximilian S. Hofmayera, Jeffrey M. Hammanna, Gérard Cahiezb, Paul Knochel*a
  • aDepartment of Chemistry, Ludwig-Maximilians-Universität München, Butenandtstraße 5–13, Haus F, 81377 München, Germany   Email: Paul.Knochel@cup.uni-muenchen.de
  • bInstitut de Recherche de Chimie Paris, CNRS, Chimie ParisTech, 11 Rue Pierre et Marie Curie, 75005 Paris, France
Further Information

Publication History

Received: 04 July 2017

Accepted after revision: 03 August 2017

Publication Date:
30 August 2017 (eFirst)

Abstract

An iron-catalyzed cross-coupling between di(hetero)arylmanganese reagents and primary and secondary alkyl halides is reported. No rearrangement of secondary alkyl halides to unbranched products was observed in these C–C bond-forming reactions.

Supporting Information