Synlett
DOI: 10.1055/s-0036-1590973
letter
© Georg Thieme Verlag Stuttgart · New York

Highly Active Manganese-Mediated Acylation of Alcohols with Acid Chlorides or Anhydrides

Seong-Ryu Joo, Young-Jin Youn, Young-Ran Hwang, Seung-Hoi Kim*
  • Department of Chemistry, Dankook University, 119 Anseo Cheonan, 31116, Republic of Korea   Email: kimsemail@dankook.ac.kr
Further Information

Publication History

Received: 07 June 2017

Accepted after revision: 03 July 2017

Publication Date:
24 August 2017 (eFirst)

Abstract

To explore further the practical uses of highly active manganese (Mn*), a variety of alcohols were treated with Mn*, and the resulting complexes were coupled with acid chlorides and/or acetic anhydride in the absence of any extra catalyst. The subsequent reactions took place smoothly under mild conditions, providing the corresponding O-acylation products in good to excellent isolated yields.