Hypervalent Iodine Chemistry as a Platform for Aerobic Oxidation Catalysis

Asim Maity; David C. Powers

doi:10.1055/s-0037-1610338

Synlett, Table of Contents

Synlett 2019; 30(03): 257-262
DOI: 10.1055/s-0037-1610338

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Hypervalent Iodine Chemistry as a Platform for Aerobic Oxidation Catalysis

Asim Maity

,

David C. Powers *

Department of Chemistry, Texas A&M University, 3255 TAMU, 580 Ross St, College Station, Texas 77843, USA Email: david.powers@chem.tamu.edu

› Author Affiliations

Abstract

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Abstract

Here, we highlight the recent development of aerobic oxidation catalysis via hypervalent I(III) and I(V) intermediates. The described chemistry intercepts reactive intermediates generated during aldehyde autoxidation to accomplish the oxidation of aryl iodides. The aerobically generated hypervalent iodine intermediates are utilized to couple an array of substrate functionalization chemistry to the reduction of O₂.

1 Introduction

2 Chemistry of Aerobically Generated I(III) Intermediates

3 Chemistry of Aerobically Generated I(V) Intermediates

4 Conclusions

Key words

aerobic oxidation - hypervalent iodine - organocatalysis - sustainable synthesis

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References

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