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Synlett 2019; 30(06): 685-693
DOI: 10.1055/s-0037-1610339
DOI: 10.1055/s-0037-1610339
account
Pd-Catalyzed C–H Silylation Reactions with Disilanes
The work was supported by the National Natural Science Foundation of China (21372176 and 21672162) and Shanghai Science and Technology Commission (14DZ2261100).
Further Information
Publication History
Received: 09 October 2018
Accepted after revision: 29 October 2018
Publication Date:
18 December 2018 (online)
Abstract
Pd-catalyzed C–H silylation reactions remain underdeveloped. General strategies usually rely on the use of complex bidentate directing groups. C,C-Palladacycles exhibit extremely high reactivity towards hexamethyldisilane and can be disilylated very efficiently. The C,C-palladacycles are prepared through halide-directed C–H activation. This account introduces Pd-catalyzed C–H silylation reactions with disilanes as the silyl source, and is focused on studies on the silylation of C,C-palladacycles.
1 Introduction and Background
2 Allylic C–H Silylation Reaction
3 Coordinating-Ligand-Directed C–H Silylation Reaction
4 Disilylation of C(sp2),C(sp2)-Palladacycles That are Generated by C(sp2)–H activation
5 Disilylation of C(sp2),C(sp3)-Palladacycles That are Generated by C(sp3)–H Activation
6 Disilylation of C,C-Palladacycles That are Generated through Domino Processes
7 Summary and Outlook
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