[(bpy)CuSCF3]: A Practical and Efficient Reagent for the Construction of C–SCF3 Bonds

Yangjie Huang; Mengjia Zhang; Qi Lin; Zhiqiang Weng

doi:10.1055/s-0040-1707211

Synlett, Inhaltsverzeichnis

Synlett 2021; 32(02): 109-118
DOI: 10.1055/s-0040-1707211

account

[(bpy)CuSCF₃]: A Practical and Efficient Reagent for the Construction of C–SCF₃ Bonds

Authors

Yangjie Huang

^aFujian Engineering Research Center of New Chinese lacquer Material, Ocean College, Minjiang University, Fuzhou, 350108, P. R. of China
Mengjia Zhang

^bFujian Provincial Key Laboratory of Electrochemical Energy Storage Materials, College of Chemistry, Fuzhou University, Fuzhou, 350108, P. R. of China eMail: zweng@fzu.edu.cn
Qi Lin∗

^aFujian Engineering Research Center of New Chinese lacquer Material, Ocean College, Minjiang University, Fuzhou, 350108, P. R. of China
Zhiqiang Weng∗

^aFujian Engineering Research Center of New Chinese lacquer Material, Ocean College, Minjiang University, Fuzhou, 350108, P. R. of China

^bFujian Provincial Key Laboratory of Electrochemical Energy Storage Materials, College of Chemistry, Fuzhou University, Fuzhou, 350108, P. R. of China eMail: zweng@fzu.edu.cn

Abstract

Alle Artikel dieser Rubrik

Abstract

In this account, we summarize recent work on the direct introduction of the SCF₃ group by using [(bpy)CuSCF₃] as trifluoromethylthiolating reagent. A number of efficient and convenient strategies have been disclosed for the synthesis of trifluoromethylthiolated compounds, including trifluoromethylthiolation of aryl, alkenyl, and alkyl halides, and arylboronic acids. These reactions afford various trifluoromethyl sulfides in good yields.

1 Introduction

2 Synthesis of [(bpy)CuSCF₃]

3 Trifluoromethylthiolation of Aryl Halides

4 Trifluoromethylthiolation of Alkenyl Halides

5 Trifluoromethylthiolation of Alkyl Halides

6 Miscellaneous

7 Conclusion

Key words

trifluoromethylthiolation - copper - fluorine - trifluoromethylthiolating reagent

Volltext

Referenzen

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