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Synlett 1992; 1992(7): 579-581
DOI: 10.1055/s-1992-21422
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New Efficient Synthesis of 1-Aminocyclopropanecarboxylic Acid

Elena Buñuel* , Carlos Cativiela, María D. Diaz-de-Villegas, Ana I. Jimenez
  • *Instituto de Ciencia de Materiales de Aragón, Departamento de Química Orgánica, Universidad de Zaragoza-CSIC, E-50009 Zaragoza, Spain
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Publication Date:
08 March 2002 (online)

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Methyl 2-[bis(methylthio)methyleneamino]acrylate (1) was efficiently converted into methyl 1-[bis(methylthio)-methyleneamino]cyclopropanecarboxylate (3) by reaction with diazomethane. This transformation provides a novel and efficient route to 1-aminocyclopropanecarboxylic acid (ACC), which is found in many plants.