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Synlett 1993; 1993(9): 696-698
DOI: 10.1055/s-1993-22576
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Synthesis of Polypropionate-Derived Acyclic Systems: Diastereoselective Hydroboration of Highly-Functionalized Trisubstituted Olefins

Lisa D. Coutts* , Charles L. Cywin, James Kallmerten
  • *Department of Chemistry, Syracuse University, Syracuse, New York 13244-4100, USA
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Publikationsdatum:
19. März 2002 (online)

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Hydroboration-oxidation of trisubstituted olefins 2 occurs with exclusive Kishi-Houk stereoselectivity and is accompanied by the stereodependent, collateral cleavage of allylic and homoallylic acetals.