Download PDF
Synlett 1994; 1994(8): 627-628
DOI: 10.1055/s-1994-22951
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Synthesis of α-Alkinylenamines by Trimethylsilanolate-Induced α-Deprotonation of Propyne Iminium Salts

Martina Brunner* , Robert Reinhard, Rainer Rahm, Gerhard Maas
  • *Fachbereich Chemie, Universität Kaiserslautern, Erwin-Schrödinger-Straße, D-67663 Kaiserslautern, Germany
Further Information

Publication History

Publication Date:
18 September 2002 (online)

 PDF Download  Permissions and Reprints All articles of this category

Iminium salts bearing an α-CH group are efficiently deprotonated with sodium trimethylsilanolate in a non-aqueous reaction medium. In this manner, little known α-alkinylenamines can be obtained from propyne iminium triflates.