Chemoenzymatic Synthesis of Azasugars: D-Talo- and D-Manno-1-Deoxynojirimycin

Carl R. Johnson; Adam Golebiowski; Elke Schoffers; Hari Sundram; Matthew P. Braun

doi:10.1055/s-1995-4967

Synlett 1995; 1995(4): 313-314
DOI: 10.1055/s-1995-4967

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Chemoenzymatic Synthesis of Azasugars: D-Talo- and D-Manno-1-Deoxynojirimycin

Carl R. Johnson^* , Adam Golebiowski, Elke Schoffers, Hari Sundram, Matthew P. Braun

^*Department of Chemistry, Wayne State University, Detroit, Michigan 48202-3489, USA

Abstract

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Enantiopure enone 1, readily available from cyclopentadiene, was used in syntheses of the title glycosidase inhibitors by routes involving ozonolysis and reductive amination.

glycosidase inhibitors - iodoenones - Pd-catalysis - Mitsunobu reaction - reductive amination

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