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Synlett 1996; 1996(1): 24-26
DOI: 10.1055/s-1996-5311
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Intramolecular Horner-Wadsworth-Emmons Olefination Route to Annulated Carbohydrates

Muriel Pipelier, Mikhail S. Ermolenko* , Angela Zampella, Alain Olesker, Gabor Lukacs
  • *Institut de Chimie des Substances Naturelles du C.N.R.S., Avenue de la Terrasse, 91198 Gif-sur-Yvette, France, Fax (1) 69077247
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Publication Date:
31 December 2000 (online)

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Depending on the length of the C-alkyl chain, vicinal β-ketophosphonates of pyranosulosides afforded, under mild basic conditions, cyclopentenone- or cyclohexenone-annulated sugars.

Horner-Wadsworth-Emmons reaction - annulated carbohydrates