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Synlett 1996; 1996(2): 175-176
DOI: 10.1055/s-1996-5348
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A New Facile Pinane Approach to Taxoid Systems Based on trans-Verbenol

H. R. Sonawane* , S. G. Sudrik, M. M. Jakkam, A. Ramani, B. Chanda1
  • *Division of Organic Chemistry: Technology, National Chemical Laboratory, Pune-411 008, India
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Publikationsdatum:
31. Dezember 2000 (online)

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The utility of C10-aldehyde(-)-8 derived from (-)-trans-Verbenol 7 is shown to offer a ready access to key intermediate (-)-11 and a number of B-secotaxane substructures 13-15 en route to advanced taxoids.

A-ring subunit - α-pinene - oxidative cleavage - B-seco taxoids