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Synlett 1996; 1996(3): 267-269
DOI: 10.1055/s-1996-5374
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An Efficient Strategy for the Synthesis of New Chiral and Prochiral Trisphosphines

Jens Holz, Achim Kless, Armin Börner*
  • *Max-Planck-Gesellschaft, Arbeitsgruppe ”Asymmetrische Katalyse” an der Universität Rostock, Buchbinderstr. 5/6, D-18055 Rostock, Germany, Fax (0381) 46 69 310/324; Bitnet aboern@chemie1.uni-rostock.de
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Publication Date:
31 December 2000 (online)

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The synthesis of a series of chiral and prochiral tris(diphenylphosphines) starting from (R,R)-tartaric acid or erythritol, respectively, is described. The new compounds based on a rigid 1,3-dioxolane ring may be useful as tridentate ligands for the complexation of several metals in different bonding modes.

Stereoselective Synthesis - Acetals - Trisphosphines - Tripodal Ligands