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Synlett 1997; 1997(4): 375-377
DOI: 10.1055/s-1997-801
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Remarkably Mild and Simple Preparations of Sulfinates, Sulfonyl Chlorides and Sulfonamides from Thioanisoles

Marc De Vleeschauwer, Jacques Yves Gauthier*
  • *Medicinal Chemistry Department, Merck Frosst Centre for Therapeutic Research, P.O. Box 1005, Pointe Claire-Dorval, Québec, CANADA, H9R 4P8
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Publication Date:
31 December 2000 (online)

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New and highly yielding procedures to convert thioanisoles into versatile sulfonyl chloride derivatives were developed by strategically taking advantage of the Pummerer reaction.

Pummerer sulfides - sulfinates - sulfonyl chlorides - sulfonamides