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Synlett 1997; 1997(8): 929-930
DOI: 10.1055/s-1997-931
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A Facile Synthesis of New Ketenimine Derivatives of α-Amino Acids

Alexander F. Khlebnikov1 , Mikhail S. Novikov2 , Rafael R. Kostikov2
  • 1Department of Chemistry, St. Petersburg State University, Universitetskii pr. 2, Petrodvorets 198904 St. Petersburg, Russia, E-mail: Alexander.Khlebnikov@pobox.spbu.ru
  • 2Department of Chemistry, St. Petersburg State University, Universitetskii pr. 2, Petrodvorets 198904 St. Petersburg, Russia
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Publication Date:
31 December 2000 (online)

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N-Vinylidene α-amino acid derivatives have been prepared from the benzophenone Schiff bases of α-amino acid esters via dichlorocarbene addition to give gem-dichloroaziridine followed by ring opening and dechlorination.

ketenimines - α-amino acid derivatives - aziridines