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Synlett 2000; 2000(3): 343-344
DOI: 10.1055/s-2000-6551
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New Synthetic Method of Alkyl Perfluoroalkyl Ethers

Masanori Tamura* , Seij Takubo, Heng-dao Quan, Akira Sekiya
  • *National Institute of Materials and Chemical Research, 1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan; Fax +81-2 98-61-45 70; E-mail: mtamura@home.nimc.go.jp
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Publication Date:
31 December 2000 (online)

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vic-Difluorination of alkyl perfluoroenol ethers proceeded with high-valence metal fluoride, such as cobalt(III) fluoride and potassium tetrafluorocobaltate, in good yields to afford alkyl perfluoroalkyl ethers.

vic-difluorination - alkyl perfluoroenol ethers - high-valence metal fluoride - chlorofluorocarbon alternatives