Download PDF
Synlett 2000; 2000(12): 1765-1768
DOI: 10.1055/s-2000-8694
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

cis-Mo(CO)4(Py)2: A Superior Reagent for the Preparation of η 3-Allyl Molybdenum Complexes

Alexander Kuhl* , John A. Christopher, Louis J. Farrugia, Philip J. Kocienski
  • *Department of Chemistry, Glasgow University, Glasgow G12 8QQ, UK; Fax +44 113 233 64014.; E-mail: p.kocienski@chem.leeds.ac.uk.
Further Information

Publication History

Publication Date:
31 December 2000 (online)

  PDF Download  Permissions and Reprints All articles of this category

A synthesis of planar chiral cationic η 3-allyl molybdenum complexes from chiral allylic benzoates benefits from the high reactivity and stereoselectivity of the inital oxidative addition step using cis-Mo(CO)4(Py)2. X-ray crystallographic evidence for the stereochemistry and mechanism of the oxidative addition step is presented.

allyl complexes - allylation - asymmetric synthesis - chirality - molybdenum - oxidative addition - planar chiral

      >