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A Highly Convenient New Methodology for the Synthesis of N-Nitrosamines from Lithium Amides
31 December 2000 (online)
N-nitrosoalkylamines were efficiently synthesized from the reaction of lithium amides with NO at atmospheric pressure using dialkylamines as starting materials. With asymmetric amines stereoselectivity is observed giving rise to different amounts of E and Z isomers.
nitrosamines - nitrosation - lithium amides - NO reactivity - alkyl nitrosamines